Synthesis of new β-hydroxylated and β-carboxylated bisquaternary ammonium salts containing fluorinated spacer groups
作者： Cécile Bassilana , Benjamin Martin , Aimé Cambon
DOI: 10.1016/S0022-1139(98)00266-8
关键词: Methyl iodide 、 Diol 、 Chemistry 、 Reactive intermediate 、 Ammonium 、 Cationic polymerization 、 Polymer chemistry 、 Organic chemistry
摘要: Abstract The synthesis of new cationic bolaphiles in which the hydrophobic section is partially fluorinated, described. These bisquaternary ammonium salts are obtained by quaternisation with methyl iodide β-hydroxyamines and β-carboxyamines, synthesised from two sufficiently reactive intermediates, namely an ω–ω′ diepoxide dibromoacetate result reaction a diol, formula HOCH 2 (CF ) 3 CH OH.
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