1,1-Dithiolato Ligands
作者： I. Haiduc
DOI: 10.1016/B978-0-12-409547-2.00884-2
关键词: Medicinal chemistry 、 Germanium 、 Molecule 、 Chemistry 、 Reagent 、 Aryl 、 Organic chemistry 、 Coordination complex 、 Deprotonation 、 Alkoxy group 、 Boron
摘要: Recent progress in the chemistry of dithiolato ligands, RR”EQ(QH) where E = P, As, C, B, Al, Si, Ge; Q = O, S, Se, Te; R = alkyl, aryl, alkoxy, is covered as an addtion to chapter included previous printed edition. About 250 new articles were published after 2001, a significant increase from edition, which contained 457 references. In deprotonated form these ligands afford large number various coordination compounds with most metals and several non-metals. Interest this type compound stimulated by their use engine oil additives, solvent extraction reagents, single molecule source for metal chalcogenides high tech (mainly electronic) materials. 1,1-dithiolato based on boron, silicon, aluminum, germanium added.
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