Phase equilibria of the Ni–Sb–Zn system at 600 °C

作者: Yuliang Zhao , Zhongxi Zhu , Yi Xie , Fucheng Yin

DOI: 10.3139/146.111419

关键词: DiffractionTernary operationMaterials scienceAnalytical chemistryScanning electron microscopePhase diagramCrystallographyTernary numeral systemSpectroscopyPhase (matter)Intermetallic

摘要: Abstract The phase equilibria of the Ni–Sb–Zn ternary system at 600 °C have been experimentally investigated using X-ray diffraction and scanning electron microscopy coupled with energy/wavelength dispersive spectroscopy. Four compounds, NiSbZn (τ1), Ni2SbZn2 (τ2), Ni3Sb2Zn (τ3) Ni4.6SbZn (τ4), were identified thirteen three-phase regions confirmed in present work. Moreover, maximum solubilities Zn NiSb NiSb2 determined to be 2.0 1.0 at.% °C, respectively; those Sb β1 γ measured up 11.8 5.3 at.%, respectively.

参考文章(26)
N. Pistofidis, G. Vourlias, S. Konidaris, E. Pavlidou, A. Stergiou, G. Stergioudis, Microstructure of zinc hot-dip galvanized coatings used for corrosion protection Materials Letters. ,vol. 60, pp. 786- 789 ,(2006) , 10.1016/J.MATLET.2005.10.013
Yuliang Zhao, Zhongxi Zhu, Fucheng Yin, Zhaohui Long, Yu Wu, 450 °C Isothermal Section of the Ni-Sb-Zn Ternary System at the Zn-Rich Corner Journal of Phase Equilibria and Diffusion. ,vol. 35, pp. 186- 194 ,(2014) , 10.1007/S11669-014-0280-3
Siyuan Peng, Meiliang Chen, Zhongxi Zhu, Wenbo Ma, Xinming Wang, Fucheng Yin, Experimental investigation of the Zn–Fe–V system at 450°C International Journal of Materials Research. ,vol. 101, pp. 1476- 1483 ,(2010) , 10.3139/146.111349
X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems Journal of Phase Equilibria. ,vol. 21, pp. 432- 442 ,(2000) , 10.1361/105497100770339608
J. Foct, P. Perrot, G. Reumont, Interpretation of the role of silicon on the galvanizing reaction based on kinetics, morphology and thermodynamics Scripta Metallurgica et Materialia. ,vol. 28, pp. 1195- 1200 ,(1993) , 10.1016/0956-716X(93)90453-Y
Duško Minić, Milan Kolarević, Dragan Manasijević, Andreja Todorović, Dragana Živković, Nadežda Talijan, Experimental investigation and thermodynamic calculations of the Ni–Sb–Zn phase diagram Materials Chemistry and Physics. ,vol. 132, pp. 402- 408 ,(2012) , 10.1016/J.MATCHEMPHYS.2011.11.045
Monojit Dutta, Ananya Mukhopadhyay, Shantanu Chakrabarti, Effect of Galvanising Parameters on Spangle Size Investigated by Data Mining Technique Isij International. ,vol. 44, pp. 129- 138 ,(2004) , 10.2355/ISIJINTERNATIONAL.44.129
Xuping Su, Nai-Yong Tang, Jim M. Toguri, 450 °C Isothermal Section of the Fe-Zn-Si Ternary Phase Diagram Canadian Metallurgical Quarterly. ,vol. 40, pp. 377- 384 ,(2001) , 10.1179/CMQ.2001.40.3.377
Tian Hou, Zhongxi Zhu, Yuliang Zhao, Fucheng Yin, Zhi Li, Yongxiong Liu, 450 °C Isothermal Section of the Fe-Al-Sb Ternary Phase Diagram Journal of Phase Equilibria and Diffusion. ,vol. 34, pp. 188- 195 ,(2013) , 10.1007/S11669-013-0223-4