作者: R. E. W. Jansson , N. R. Tomov
DOI: 10.1007/BF00615479
关键词: Emulsion 、 Batch reactor 、 Hypobromite 、 Benzaldehyde 、 Inorganic chemistry 、 Benzyl alcohol 、 Continuous stirred-tank reactor 、 Electrochemistry 、 Transfer agent 、 Chemistry
摘要: The oxidation of benzyl alcohol by electrogenerated hypobromite in a two-phase emulsion has been studied using quaternary ammonium salt as phase transfer agent. performances stirred-tank batch reactor and bipolar electrochemical pump cell have compared the differences found are discussed terms different mixing/transport/reaction regimes two cells. Benzaldehyde can be produced at rate 0.2 mol h−1 dm−2 electrode area for 4.20 kWh kg−1.