Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion
作者： Dong-Hoon Won , Motoki Toganoh , Hidemitsu Uno , Hiroyuki Furuta
DOI: 10.1039/B906018A
关键词: Pyrrole 、 Deprotonation 、 Porphyrin 、 Polymer chemistry 、 Photochemistry 、 Ion 、 Single crystal 、 Chemistry 、 Inorganic chemistry
摘要: Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl−, Br−, and I− anions at the peripheral N–H, while deprotonation proceeds with F−, H2PO4−, OH− in CH2Cl2 solution; neutral anionic structures 1-Pt were characterized by single crystal X-ray diffraction analysis.
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