Synthesis of short-channeled amino-functionalized SBA-15 and its beneficial applications in base-catalyzed reactions

作者: Sujandi , Eko Adi Prasetyanto , Sang-Eon Park

DOI: 10.1016/J.APCATA.2008.08.020

关键词: Knoevenagel condensationMesoporous materialChemistryStereochemistryNitroaldol reactionHeterogeneous catalysisChemical engineeringSubstrate (chemistry)CopolymerCatalysisHydrolysis

摘要: Amino-functionalized-SBA-15 catalysts with nanostructured hexagonal platelet morphologies were synthesized directly by using microwave synthesis from the hydrolysis and co-condensation of aminopropyltriethoxysilane (APTES) and sodium metasilicate under a strong acidic condition with the Pluronic P123 triblock copolymer as a structure-directing agent. The amino-functionalized-SBA-15 catalysts were proven by SEM and TEM techniques to have very short channels in the range of 200–300nm perpendicular to the …

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