A synthetic model of the nonheme iron–superoxo intermediate of cysteine dioxygenase
作者： Anne A. Fischer , Sergey V. Lindeman , Adam T. Fiedler
DOI: 10.1039/C8CC06247A
关键词: Cysteine dioxygenase 、 Yield (chemistry) 、 Chemistry 、 Nonheme iron 、 Stereochemistry 、 Superoxide radical
摘要: … these features arise from either an iron–superoxo or Fe–O–O… CDO intermediate is an iron–superoxo species. This conclusion … iron-thiolate coordination – that detected an iron–superoxo …
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