Exploring the interfacial neutral pH region of Pt(111) electrodes
作者： Ricardo Martínez-Hincapié , Paula Sebastián-Pascual , Víctor Climent , Juan M. Feliu
DOI: 10.1016/J.ELECOM.2015.06.005
关键词: Charge (physics) 、 Chemistry 、 Neutral ph 、 Single crystal 、 Double layer (biology) 、 Analytical chemistry 、 Electrode 、 Interphase 、 Ph range 、 Charge displacement
摘要: Abstract The interfacial properties of Pt(111) single crystal electrodes have been investigated in the pH range 3 4 are used. Total charge curves obtained at different pHs from integration voltammetric currents combination with CO displacement experiments. Analysis composition interphase as a function provides information for understanding notion pH.
core.ac.uk
elsevier.com
sci-hub.se 参考文章(19)
A. N. Frumkin, O. A. Petrii, B. B. Damaskin, Potentials of Zero Charge Springer, Boston, MA. pp. 221- 289 ,(1980) , 10.1007/978-1-4615-6684-7_5
Sergio Trasatti, Enn Lust, The Potential of Zero Charge Modern Aspects of Electrochemistry. pp. 1- 215 ,(2002) , 10.1007/0-306-46917-0_1
E. Gileadi, S. D. Argade, Potential of zero charge ,(1965)
Sergio Trasatti, The Electrode Potential Springer, Boston, MA. pp. 45- 81 ,(1980) , 10.1007/978-1-4615-6684-7_2
Michael J. Weaver, Potentials of Zero Charge for Platinum(111)−Aqueous Interfaces: A Combined Assessment from In-Situ and Ultrahigh-Vacuum Measurements Langmuir. ,vol. 14, pp. 3932- 3936 ,(1998) , 10.1021/LA9801054
V. Climent, N. García-Araez, E. Herrero, J. Feliu, Potential of zero total charge of platinum single crystals: A local approach to stepped surfaces vicinal to Pt(111) Russian Journal of Electrochemistry. ,vol. 42, pp. 1145- 1160 ,(2006) , 10.1134/S1023193506110012
Rubén Rizo, Elton Sitta, Enrique Herrero, Víctor Climent, Juan M. Feliu, Towards the understanding of the interfacial pH scale at Pt(1 1 1) electrodes Electrochimica Acta. ,vol. 162, pp. 138- 145 ,(2015) , 10.1016/J.ELECTACTA.2015.01.069
A. Lachenwitzer, N. Li, J. Lipkowski, Determination of the acid dissociation constant for bisulfate adsorbed at the Pt(111) electrode by subtractively normalized interfacial Fourier transform infrared spectroscopy Journal of Electroanalytical Chemistry. ,vol. 532, pp. 85- 98 ,(2002) , 10.1016/S0022-0728(02)00759-3
J.O'M. Bockris, S.D. Argade, E. Gileadi, The determination of the potential of zero charge on solid metals Electrochimica Acta. ,vol. 14, pp. 1259- 1283 ,(1969) , 10.1016/0013-4686(69)87021-0
Angel Cuesta, Measurement of the surface charge density of CO-saturated Pt(1 1 1) electrodes as a function of potential: the potential of zero charge of Pt(1 1 1) Surface Science. ,vol. 572, pp. 11- 22 ,(2004) , 10.1016/J.SUSC.2004.08.014