Molecular beam electric resonance spectroscopy of the nitric oxide dimer
作者： Colin M. Western , Patrick R.R. Langridge-Smith , Brian J. Howard , Stewart E. Novick
DOI: 10.1080/00268978100102341
关键词: Electric dipole moment 、 Electron 、 Analytical chemistry 、 Spectroscopy 、 Resonance 、 Quadrupole 、 Dimer 、 Chemistry 、 Atomic physics 、 Molecular beam 、 Dipole
摘要: Microwave and radiofrequency spectra have been observed for (NO)2 using the technique of molecular beam electric resonance spectroscopy. Precise values determined rotational, nuclear quadrupole coupling spin-rotation constants ground electronic state treated as a singlet state. The obtained are A = 25829·4803(20) MHz, B 5614·3093(4) C 4605·4396(12) MHz xaa -4·0652(2) xbb - xcc -8·5498(6) caa 10·4(5) kHz, cbb 13·8(4) ccc 0·8(4) kHz. dipole moment has also determined: μ 0·17120(2) D. From these data is interpreted to symmetric cis-planar structure with structural parameters r NN 2·33(12) A, NO 1·15(1) ∠NNO 95(5), 1/2(r + NO) 2·444(8) A. nitrogen nuclei demonstrate that little electron rearrangement occurs on dimer formation. In addition indicate unpaired π electrons lie in plane imply...
harvard.edu
sci-hub.se 参考文章(32)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
Gerhard Herzberg, Klaus-Peter Huber, Constants of diatomic molecules ,(1979)
A. Anderson, B. Lassier-Govers, Infrared and raman spectra of crystalline nitric oxide Chemical Physics Letters. ,vol. 50, pp. 124- 128 ,(1977) , 10.1016/0009-2614(77)80694-5
G. H. Shortley, The Theory of Atomic Spectra ,(1935)
Carl E. Dinerman, George E. Ewing, Infrared Spectrum, Structure, and Heat of Formation of Gaseous (NO)2 The Journal of Chemical Physics. ,vol. 53, pp. 626- 631 ,(1970) , 10.1063/1.1674038
W. J. Dulmage, E. A. Meyers, W. N. Lipscomb, On the crystal and molecular structure of N2O2 Acta Crystallographica. ,vol. 6, pp. 760- 764 ,(1953) , 10.1107/S0365110X53002179
Frank P. Billingsley, Multiconfiguration self‐consistent‐field calculation of the dipole moment function and potential curve of NO(X2Π) Journal of Chemical Physics. ,vol. 62, pp. 864- 874 ,(1975) , 10.1063/1.430537
Alan H. Brittain, A. Peter Cox, Robert L. Kuczkowski, Microwave spectrum, structure, low frequency vibrations, dipole moment and quadrupole coupling constants of dinitrogen trioxide Transactions of the Faraday Society. ,vol. 65, pp. 1963- 1974 ,(1969) , 10.1039/TF9696501963
E. Forte, H. Van Den Bergh, The heat of formation of the nitric oxide dimer and its UV spectrum Chemical Physics. ,vol. 30, pp. 325- 331 ,(1978) , 10.1016/0301-0104(78)87004-9
Robert L. Scott, Dimerization of gaseous nitric oxide Molecular Physics. ,vol. 11, pp. 399- 401 ,(1966) , 10.1080/00268976600101221