Phosphorescence of adsorbed ionic organic molecules at room temperature.

作者: E. M. Schulman , C. Walling

DOI: 10.1126/SCIENCE.178.4056.53

关键词: Ionic bondingPhosphorescencePhenolsOrganic moleculesOxygenSpectral lineChemistryAdsorptionQuenching (fluorescence)PhotochemistryInorganic chemistry

摘要: Many salts of polynuclear carboxylic acids, phenols, amines, and sulfonic acids adsorbed on paper, silica, alumina, other substrates exhibit strong triplet phosphorescence at room temperature, with no evidence quenching by oxygen. No has been observed nonionic materials. The spectra are similar to those frozen solutions -196 degrees C, the technique provides a simple means demonstrating phenomena, identifying unknown materials, investigating states.

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