Preparation of highly stable superhydrophobic TiO2 surfaces with completely suppressed photocatalytic activity
作者： Kwang-Dae Kim , Hyun Ook Seo , Chae Won Sim , Myung-Geun Jeong , Young Dok Kim
DOI: 10.1016/J.PORGCOAT.2012.11.010
关键词: Nanotechnology 、 Polydimethylsiloxane 、 Nanoparticle 、 Organic molecules 、 Chemical engineering 、 Layer (electronics) 、 Contact angle 、 Nanostructure 、 Uv protection 、 Materials science 、 Photocatalysis
摘要: Abstract TiO 2 nanoparticles with a mean size of 20–30 nm were covered by ultrathin polydimethylsiloxane (PDMS) film, which shows hydrophobic properties. Surfaces consisting the PDMS-coated particles showed water contact angles close to 170°. In contrast films organic molecules, can be photocatalytically decomposed on in presence UV light, PDMS-coating was highly stable. The completely suppressed photocatalytic activity . unique properties exploited for protection layer and self-cleaning surfaces.
sci-hub.se 参考文章(20)
Wilson A. Lee, Nadine Pernodet, Bingquan Li, Chien H. Lin, Eli Hatchwell, Miriam H. Rafailovich, Multicomponent polymer coating to block photocatalytic activity of TiO2 nanoparticles. Chemical Communications. pp. 4815- 4817 ,(2007) , 10.1039/B709449C
K.O. Awitor, A. Rivaton, J.-L. Gardette, A.J. Down, M.B. Johnson, Photo-protection and photo-catalytic activity of crystalline anatase titanium dioxide sputter-coated on polymer films Thin Solid Films. ,vol. 516, pp. 2286- 2291 ,(2008) , 10.1016/J.TSF.2007.08.005
Mengnan Qu, Guangyu Zhao, Xiaoping Cao, Junyan Zhang, Biomimetic fabrication of lotus-leaf-like structured polyaniline film with stable superhydrophobic and conductive properties. Langmuir. ,vol. 24, pp. 4185- 4189 ,(2008) , 10.1021/LA703284F
Yudi Rahmawan, Myoung-Woon Moon, Kyung-Suk Kim, Kwang-Ryeol Lee, Kahp-Yang Suh, Wrinkled, dual-scale structures of diamond-like carbon (DLC) for superhydrophobicity. Langmuir. ,vol. 26, pp. 484- 491 ,(2010) , 10.1021/LA902129K
J. H. Oh, H. W. Yeom, Y. Hagimoto, K. Ono, M. Oshima, N. Hirashita, M. Nywa, A. Toriumi, A. Kakizaki, Chemical structure of the ultrathin SiO 2 / S i ( 100 ) interface: An angle-resolved Si 2 p photoemission study Physical Review B. ,vol. 63, pp. 205310- ,(2001) , 10.1103/PHYSREVB.63.205310
Andrew Mills, Matthew Crow, In situ, continuous monitoring of the photoinduced superhydrophilic effect : Influence of UV-type and ambient atmospheric and droplet composition Journal of Physical Chemistry C. ,vol. 111, pp. 6009- 6016 ,(2007) , 10.1021/JP068327V
Jiaobing Wang, Yanfei Shen, Stefanie Kessel, Paulo Fernandes, Kaname Yoshida, Shiki Yagai, Dirk G. Kurth, Helmuth Möhwald, Takashi Nakanishi, Self-assembly made durable: water-repellent materials formed by cross-linking fullerene derivatives. Angewandte Chemie. ,vol. 48, pp. 2166- 2170 ,(2009) , 10.1002/ANIE.200900106
Pavel A. Levkin, Frantisek Svec, Jean M. J. Fréchet, Porous Polymer Coatings: a Versatile Approach to Superhydrophobic Surfaces Advanced Functional Materials. ,vol. 19, pp. 1993- 1998 ,(2009) , 10.1002/ADFM.200801916
Ho Sun Lim, Donghoon Kwak, Dong Yun Lee, Seung Goo Lee, Kilwon Cho, UV-Driven Reversible Switching of a Roselike Vanadium Oxide Film between Superhydrophobicity and Superhydrophilicity Journal of the American Chemical Society. ,vol. 129, pp. 4128- 4129 ,(2007) , 10.1021/JA0692579
Ki-jeong Kim, Junghun Choi, Hangil Lee, Han-Koo Lee, Tai-Hee Kang, Young-Hwan Han, Byung-Cheol Lee, Sehun Kim, Bongsoo Kim, None, Effects of 1 MeV electron beam irradiation on multilayer graphene grown on 6H-SiC(0001) Journal of Physical Chemistry C. ,vol. 112, pp. 13062- 13064 ,(2008) , 10.1021/JP805141E