Solvent extraction of cadmium from sulfate solution with di-(2-ethylhexyl) phosphoric acid diluted in kerosene
作者： Vinay Kumar , Manoj Kumar , Manis Kumar Jha , Jinki Jeong , Jae-chun Lee
DOI: 10.1016/J.HYDROMET.2008.10.010
关键词: Inorganic chemistry 、 Sulfate 、 Di-(2-ethylhexyl)phosphoric acid 、 Chemistry 、 Cadmium 、 Phosphoric acid 、 Solvent 、 Sulfuric acid 、 Hydrometallurgy 、 Diluent 、 Industrial and Manufacturing Engineering 、 Materials Chemistry 、 Metals and Alloys
摘要: Abstract In the present paper, solvent extraction process has been used for of cadmium from sulfate solution using di-(2-ethylhexyl) phosphoric acid (D2EHPA) with 1% isodecanol in kerosene diluent expected industrial effluents or leaching ores/secondary materials. Different parameters such as pH, contact time, extractant concentration, O/A ratio etc. were investigated. Results demonstrated that quantitative was feasible 4.45 mM feed single stage at equilibrium pH 4.5, time 2 min and 1:1 0.15 mM D2EHPA. The mechanism by D2EHPA could be represented Cd 2 + + 3/2 (H A ) org ⇔ CdA (HA) + 2H . loading capacity determined to ∼ 8.9 mM cadmium. loaded effectively stripped 180 g/L sulfuric acid. metal salt produced electrolysis crystallization solution.
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sci-hub.se 参考文章(20)
A. W. Ashbrook, G. M. Ritcey, Solvent extraction : principles and applications to process metallurgy Published in <b>1984</b> in Amsterdam by Elsevier. ,(1979)
Abdelhamid Mellah, Djafer Benachour, The solvent extraction of zinc, cadmium and chromium from phosphoric acid solutions by tri-n butyl phosphate in kerosene diluent Separation and Purification Technology. ,vol. 56, pp. 220- 224 ,(2007) , 10.1016/J.SEPPUR.2007.01.037
A. Almela, M.P. Elizalde, Solvent extraction of cadmium (II) from acidic media by Cyanex 302 Hydrometallurgy. ,vol. 37, pp. 47- 57 ,(1995) , 10.1016/0304-386X(94)00012-R
Danuza Pereira Mantuano, Germano Dorella, Renata Cristina Alves Elias, Marcelo Borges Mansur, Analysis of a hydrometallurgical route to recover base metals from spent rechargeable batteries by liquid–liquid extraction with Cyanex 272 Journal of Power Sources. ,vol. 159, pp. 1510- 1518 ,(2006) , 10.1016/J.JPOWSOUR.2005.12.056
M. Sadegh Safarzadeh, M.S. Bafghi, D. Moradkhani, M. Ojaghi Ilkhchi, A review on hydrometallurgical extraction and recovery of cadmium from various resources Minerals Engineering. ,vol. 20, pp. 211- 220 ,(2007) , 10.1016/J.MINENG.2006.07.001
Archana Agrawal, K.K. Sahu, Kinetic and isotherm studies of cadmium adsorption on manganese nodule residue Journal of Hazardous Materials. ,vol. 137, pp. 915- 924 ,(2006) , 10.1016/J.JHAZMAT.2006.03.039
B. Ramachandra Reddy, D. Neela Priya, J. Rajesh Kumar, Solvent extraction of cadmium (II) from sulphate solutions using TOPS 99, PC 88A, Cyanex 272 and their mixtures Hydrometallurgy. ,vol. 74, pp. 277- 283 ,(2004) , 10.1016/J.HYDROMET.2004.06.001
K. Nazari, A. Ghadiri, H. Babaie, Elimination of cadmium from wet process phosphoric acid with Alamine 336 Minerals Engineering. ,vol. 18, pp. 1233- 1238 ,(2005) , 10.1016/J.MINENG.2005.07.008
Chung-Hsu Wang, Ying-Chu Hoh, The effect of pH on cadmium extraction by Lix 34 Hydrometallurgy. ,vol. 8, pp. 161- 171 ,(1982) , 10.1016/0304-386X(82)90042-1
M.B Mansur, M.J Slater, E.C Biscaia, Equilibrium analysis of the reactive liquid–liquid test system ZnSO4/D2EHPA/n-heptane Hydrometallurgy. ,vol. 63, pp. 117- 126 ,(2002) , 10.1016/S0304-386X(01)00211-0