Phase diagrams and electrical properties of (Bi1/2Na1/2)TiO3-based solid solutions

作者: Yuji Hiruma , Hajime Nagata , Tadashi Takenaka

DOI: 10.1063/1.3043588

关键词: Materials sciencePermittivityPiezoelectricityAnalytical chemistrySolid solutionFerroelectric ceramicsDielectricPhase diagramPhase transitionCeramic

摘要: In this study, we demonstrated the relationship between phase diagrams and electrical properties of (Bi1/2Na1/2)TiO3 (BNT)-based solid solutions. (1−x)(Bi1/2Na1/2)TiO3–xNaNbO3 (1−x)(Bi1/2Na1/2)TiO3–xKNbO3 (abbreviated to BNT-NN100x BNT-KN100x) ceramics were prepared by a conventional ceramic fabrication process, (1−x)(Bi1/2Na1/2)TiO3–x(Bi1/2K1/2)TiO3 BNKT100x) was for comparison. We revealed transition temperatures, such as depolarization temperature Td, rhombohedral-tetragonal TR-T, Tm maximum dielectric constant, from dependence using poled unpoled specimens. As result, it shown that BNT-based solutions form three types diagrams. addition, clarified BNT-NN100x, BNT-KN100x, BNKT100x. The piezoelectric we...

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