Mechanical properties of nylon-6 after treatment with metal halides
作者： A.P More , A.M Donald
DOI: 10.1016/0032-3861(93)90253-7
关键词: Crazing 、 Metal halides 、 Stiffening 、 Nylon 6 、 Stereochemistry 、 Intermolecular force 、 Deformation (mechanics) 、 Spectroscopy 、 Modulus 、 Composite material 、 Chemistry
摘要: Abstract Conditioning of nylon-6 by immersion in metal chloride solutions modifies the mode deformation under an applied tensile stress. Infra-red spectroscopy salt-treated films shows significant modification spectrum, indicating changes intermolecular bonding. Modulus measurements support hypothesis that bonding nylon results some chain stiffening. This stiffening network chains reduces mobility is required for shear deformation. turn leads to onset scission crazing. NaCl, however, spectroscopically no evidence nylon-salt interactions having occurred. The behaviour both thin-film and bulk samples NaCl-treated reflect absence any salt-amide interaction.
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sci-hub.se 参考文章(23)
Edward J. Kramer, Microscopic and molecular fundamentals of crazing Springer Berlin Heidelberg. pp. 1- 56 ,(1983) , 10.1007/BFB0024055
Edward J. Kramer, Larry L. Berger, Fundamental processes of craze growth and fracture Springer, Berlin, Heidelberg. pp. 1- 68 ,(1990) , 10.1007/BFB0018018
Michael G. Wyzgoski, Glen E. Novak, Stress cracking of nylon polymers in aqueous salt solutions Journal of Materials Science. ,vol. 22, pp. 1715- 1723 ,(1987) , 10.1007/BF01132397
Samuel Krimm, Jagdeesh Bandekar, Vibrational spectroscopy and conformation of peptides, polypeptides, and proteins. Advances in Protein Chemistry. ,vol. 38, pp. 181- 364 ,(1986) , 10.1016/S0065-3233(08)60528-8
Bruce D. Lauterwasser, Edward J. Kramer, Microscopic mechanisms and mechanics of craze growth and fracture Philosophical Magazine. ,vol. 39, pp. 469- 495 ,(1979) , 10.1080/01418617908239285
A. Peterlin, Molecular model of drawing polyethylene and polypropylene. Journal of Materials Science. ,vol. 6, pp. 490- 508 ,(1971) , 10.1007/BF00550305
A.P. More, A.M. Donald, The effect of metal halides on the deformation mechanism of thin films of nylon Polymer. ,vol. 33, pp. 4081- 4086 ,(1992) , 10.1016/0032-3861(92)90609-Z
Hyo‐gun Kim, Paul J. Harget, Glass transition temperature of nylon 6—Inorganic salt mixtures Journal of Applied Physics. ,vol. 50, pp. 6072- 6076 ,(1979) , 10.1063/1.325796
Athene M. Donald, Edward J. Kramer, Plane stress deformation zones at crack tips in polycarbonate Journal of Materials Science. ,vol. 16, pp. 2967- 2976 ,(1981) , 10.1007/BF00540301
G. H. Michler, Correlations between molecular weight, morphology and micromechanical deformation processes of polyethylenes Colloid and Polymer Science. ,vol. 270, pp. 627- 638 ,(1992) , 10.1007/BF00654039