Divacant polyoxotungstates: reactivity of the gamma-decatungstates [γ-XW10O36]8-(X = Si, Ge).
作者： Bassem S. Bassil , Ulrich Kortz
DOI: 10.1039/C1DT10845J
关键词: Nucleophile 、 Crystallography 、 Tungsten 、 Metal ions in aqueous solution 、 Inorganic chemistry 、 Ion 、 Reactivity (chemistry) 、 Isomerization 、 Electrophile 、 Chemistry 、 Polyoxometalate
摘要: The dilacunary, Keggin-based gamma-decatungstate ions [γ-XW10O36]8− (X = Si, Ge) {XW10} exhibit an exciting and versatile solution chemistry, which is probably unmatched by any other lacunary polytungstate. reactivity of in the presence, even absence, electrophiles, includes loss/gain tungsten, isomerization, dimerization. Ever since syntheses structures were reported, many research groups around world have investigated these polyanions towards nucleophiles (mostly d-block metal ions) different products with various shape, size composition obtained. Here we provide overview state-of-the-art this subarea polyoxometalate a focus on synthetic structural aspects.
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