作者: Jette Eriksen , Ole Mønsted , Lene Mønsted
关键词: Methylglyoxal 、 Catalysis 、 Medicinal chemistry 、 Stereochemistry 、 Organometallic chemistry 、 Stoichiometry 、 Glyceraldehyde 、 Chemistry 、 Rhodium 、 Lactic acid 、 Ligand
摘要: The transformation of methylglyoxal and 1,3–dihydroxyacetone glyceraldehyde into lactic acid can be catalyzed by cis- tetraaminediaquarhodium(III) complexes ethane-1,2–diamine the macrocyclic racemic 5,5,7,12,12,14–hexamethyl-1,4,8,11– tetraazacyclotetradecane ligand. detailed stoichiometry this process has been investigated isotopic labelling studies 1H 13C-n.m.r. spectroscopy.