Selective distribution of dopants among MO 6 octahedra in RbTi 0.927 Nb 0.056 Er 0.017 OPO 4 : a neutron diffraction study
作者： JJ Carvajal , JL Garcı́a-Muñoz , R Solé , Jna Gavaldà , J Massons
DOI: 10.1016/S0022-4596(02)00172-X
关键词: Dopant 、 Doping 、 Octahedron 、 Photoluminescence 、 Ion 、 Neutron diffraction 、 Chemistry 、 Second-harmonic generation 、 Nonlinear optics 、 Crystallography 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Materials Chemistry 、 Electronic, Optical and Magnetic Materials 、 Condensed matter physics 、 Ceramics and Composites
摘要: Abstract Codoping RbTiOPO 4 crystals (RTP) with Er 3+ and Nb 5+ is interesting in order to merge the rare earth ion photoluminescence non-linear optical properties of matrix, favouring self-induced effects. Using RTP doped , a concentration similar that obtained other laser matrices was achieved. In this work, structure RbTi 0.927 0.056 0.017 OPO has been thoroughly studied by high-resolution neutron diffraction. Particular attention paid positions occupied distortion their respective coordination polyhedra. Finally, second-harmonic generation efficiency sample determined compared members family.
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