Optical resolution of amine N-oxide by diastereoisomeric complex formation with optically active host compound
作者： Fumio Toda , Koji Mori , Zafra Stein , Israel Goldberg
DOI: 10.1016/S0040-4039(00)99594-7
关键词: Amine gas treating 、 Chemistry 、 Oxide 、 Complex formation 、 Resolution (electron density) 、 Crystallography 、 Photochemistry 、 Optically active 、 Intermolecular interaction
摘要: Abstract Optical stereoisomers of various amine N-oxides with one or two chiral centers can effectively be resolved by selective crystalline complexation an optically active host. Intermolecular interaction schemes and absolute configurations the N-oxide guests are revealed crystallographic analyses diastereoisomeric complexes.
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