Solubility of hydrogen and deuterium in ZrCo
作者： M. Devillers , M. Sirch , R.-D. Penzhorn
DOI: 10.1016/0022-3115(93)90247-V
关键词: Intermetallic 、 Solubility 、 Deuterium 、 Hydrogen 、 Chemistry 、 Dilution 、 Nuclear chemistry 、 Physical chemistry
摘要: Abstract This paper gives first results on the solubility of hydrogen and deuterium in ZrCo composition range 2 × 10−3 K S ) H (K D was found to be 1.182 ± 0.035. The relative partial molar enthalpies Δ ∞ Q (Q = H, D) nonconfigurational or excess entropies ΔSncQ at infinite dilution were calculated −28.2 kJ/mol , −27.7 nc∞ −73.5 J/K mol −74.2 respectively. Whereas largely independent xQ nQ/nZrCo ratio intermetallic compound, negative observed increase with xQ.
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