Perfluoropolyether-Functionalized Carbon-Based Materials and Their Applications

作者: M. Sansotera , M. Gola , W. Navarrini

DOI: 10.1016/B978-0-12-803479-8.00015-2

关键词: Fluorous chemistryCarbonPolymer chemistryLithiumPolymerMaterials scienceSurface energyChemical engineeringElectrochemistryChemical resistanceLubricity

摘要: In the last decade, several carbon-based materials have been covalently functionalized with perfluoropolyethers (PFPEs) moieties, and properties of these PFPE-functionalized characterized to outline their possible applications. PFPE fluids are perfluorinated polymeric compounds which exhibit exceptional thermooxidative stability chemical resistance, high gas permeability, low surface energy, good lubricity characteristics, extended bioinertness. The covalent functionalization chains modified some typical PFPEs, such as energy were conferred surface. addition, remained thermally chemically resistant, thanks both starting materials. On basis features, applications developed in field electrochemical devices fuel cells lithium batteries, self-lubricating surfaces polymer formulation. Other separation techniques based on fluorous effect ascribable chains.

参考文章(100)
Dirk M. Guldi, Hartmut Hungerbuehler, Eberhard Janata, Klaus Dieter Asmus, Redox processes and alkylation reactions of fullerene C60 as studied by pulse radiolysis The Journal of Physical Chemistry. ,vol. 97, pp. 11258- 11264 ,(1993) , 10.1021/J100145A024
Hidekazu Touhara, Electrochemical properties of fluorinated carbon nanotubes Fluorinated Materials for Energy Conversion. pp. 89- 102 ,(2005) , 10.1016/B978-008044472-7/50032-1
Paul J. Krusic, Paul J. Fagan, Edel Wasserman, Fluoroalkylated fullerene compounds ,(1993)
M. Walbiner, H. Fischer, Rate constants for the addition of the benzyl radical to fullerene C60 in solution The Journal of Physical Chemistry. ,vol. 97, pp. 4880- 4881 ,(1993) , 10.1021/J100121A002
Dario Sianesi, Adolfo Pasetti, Costante Corti, Photooxidation of perfluoroolefins; polyperoxides and polyethers of hexafluoropropene Macromolecular Chemistry and Physics. ,vol. 86, pp. 308- 311 ,(1965) , 10.1002/MACP.1965.020860131
Maurizio Sansotera, Walter Navarrini, Pietro Cavallotti, Giuseppe Resnati, Pierangelo Metrangolo, Modification of carbonaceous materials ,(2008)
Michael Holzinger, Otto Vostrowsky, Andreas Hirsch, Frank Hennrich, Manfred Kappes, Robert Weiss, Frank Jellen, Sidewall Functionalization of Carbon Nanotubes This work was supported by the European Union under the 5th Framework Research Training Network 1999, HPRNT 1999-00011 FUNCARS. Angewandte Chemie. ,vol. 40, pp. 4002- 4005 ,(2001) , 10.1002/1521-3773(20011105)40:21<4002::AID-ANIE4002>3.0.CO;2-8
Guohui Zhang, Paul M. Kirkman, Anisha N. Patel, Anatolii S. Cuharuc, Kim McKelvey, Patrick R. Unwin, Molecular functionalization of graphite surfaces : Basal Plane versus Step Edge electrochemical activity Journal of the American Chemical Society. ,vol. 136, pp. 11444- 11451 ,(2014) , 10.1021/JA505266D
S. Banerjee, T. Hemraj-Benny, S. S. Wong, Covalent Surface Chemistry of Single‐Walled Carbon Nanotubes Advanced Materials. ,vol. 17, pp. 17- 29 ,(2005) , 10.1002/ADMA.200401340