Direct Observation ofα-Chloro-p-quinodimethane as the Real Monomer in the Gilch Polymerization Leading to Poly(p-phenylene vinylene)s
作者： Jens Wiesecke , Matthias Rehahn
关键词: Benzene 、 Materials science 、 Polymerization 、 Polymer chemistry 、 Monomer 、 Poly(p-phenylene vinylene) 、 Photochemistry 、 Conductive polymer 、 Self-condensation 、 Radical polymerization 、 Reaction mechanism 、 Organic chemistry 、 Materials Chemistry 、 Polymers and Plastics
摘要: It is the general consensus that in Gilch polymerizations the 1, 4‐bis (chloromethylene) benzene starting material first changes into p‐quinodimethane intermediates which then act …
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