INVESTIGATIONS OF THE VIBRONIC TRANSITIONS IN CS2NAERCL6

作者: B. Jeżowska-Trzebiatowska , W. Ryba-Romanowski , Z. Mazurak , J. Hanuza

DOI: 10.1016/0301-0104(80)87039-X

关键词: Crystal field theoryVibronic spectroscopyMoietyInfraredRaman spectroscopyAnalytical chemistryMolecular physicsChemistryIonAbsorption (chemistry)Magnetic susceptibility

摘要: Abstract The results of low temperature magnetic susceptibility measurements and infrared Raman spectra have been used for the determination crystal field splitting lying states Er3+ ions in Cs2NaErCl6 single crystals, calculation normal vibrations ErCl3−6 moiety. optical absorption were also measured obtained data analysis vibronic transitions ions. Assignments observed bands proposed.

参考文章(16)
Robert W. Schwartz, The electronic structure of Cs2NaEuCl6 Molecular Physics. ,vol. 30, pp. 81- 95 ,(1975) , 10.1080/00268977500101781
K.R. Lea, M.J.M. Leask, W.P. Wolf, The raising of angular momentum degeneracy of f-Electron terms by cubic crystal fields Journal of Physics and Chemistry of Solids. ,vol. 23, pp. 1381- 1405 ,(1962) , 10.1016/0022-3697(62)90192-0
F. Varsanyi, G. H. Dieke, Energy Levels of Hexagonal ErCl3 The Journal of Chemical Physics. ,vol. 36, pp. 2951- 2961 ,(1962) , 10.1063/1.1732407
D. G. Karraker, Magnetic Susceptibility of Yb3+in an Octahedral Environment The Journal of Chemical Physics. ,vol. 55, pp. 1084- 1086 ,(1971) , 10.1063/1.1676189
M. V. Hoehn, D. G. Karraker, Magnetic susceptibilities of trivalent lanthanide ions in an octahedral environment Journal of Chemical Physics. ,vol. 60, pp. 393- 397 ,(1974) , 10.1063/1.1681053
B. D. Dunlap, G. K. Shenoy, Crystal-field analysis for the susceptibility of lanthanide compounds of the formCs2NaRCl6 Physical Review B. ,vol. 12, pp. 2716- 2724 ,(1975) , 10.1103/PHYSREVB.12.2716
Larry C. Thompson, O.A. Serra, James P. Riehl, Frederick S. Richardson, Robert W. Schwartz, Emission spectra of Cs2NaTbCl6 and Cs2NaYCl6: Tb3+ Chemical Physics. ,vol. 26, pp. 393- 401 ,(1977) , 10.1016/0301-0104(77)85163-X