作者: Andrew Webber
DOI: 10.1149/1.2087287
关键词: Conductivity 、 Lithium 、 Dielectric 、 Propylene carbonate 、 Inorganic chemistry 、 Imide 、 Electrolyte 、 Chemistry 、 Viscosity 、 Trifluoromethanesulfonate
摘要: The high level of charge delocalization the anion reduces ion pairing in nonaqueous electrolytes. This overrides higher viscosity imide‐containing solutions making electrolytes much more conductive than those containing , especially low dielectric ether‐based solvent systems commonly used secondary lithium batteries. In viscous (1:1 propylene carbonate: 1,2‐dimethoxyethane) or at temperatures, imide affords less an advantage conductivity due to important role viscosity. cyclic gives and does . degree dissociation 1:1 PC:DME appears be