Electropolymerization of aniline monomer and effects of synthesis conditions on the characteristics of synthesized polyaniline thin films

作者: Sanaa El Aggadi , Nidae Loudiyi , Aicha Chadil , Zoubida El Abbassi , Abderrahim El Hourch

DOI: 10.13171/MJC102020021114SEA

关键词: ElectrodeMonomerChemistrySulfuric acidAnilinePolyanilineNuclear chemistryPlatinumCyclic voltammetryHorizontal scan rate

摘要: Electrochemical polymerization of aniline was carried on platinum (Pt) wire electrode in sulfuric acid (H 2 SO 4 ) solution by cyclic voltammetry using a conventional three-electrode cell at room temperature (20°C). The effects the electrodeposition monomer concentration, anodic potential and scan rate are discussed. conductive layer emeraldine base polyaniline (Pani) prepared this work repeating cycling between -0.24 0.9 V/SCE 50 mV/s 1 M H containing 0.1 monomer.

参考文章(37)
Layane S Rego, Jadielson LS Antonio, Claudio HB Silva, Marcelo M Nobrega, Marcia LA Temperini, Roberto M Torresi, Susana I Cordoba de Torresi, None, Electrochemical template synthesis of adherent polyaniline thin films with tubular structure Journal of Solid State Electrochemistry. ,vol. 20, pp. 983- 991 ,(2016) , 10.1007/S10008-015-2952-2
Tetsuhiko Kobayashi, Hiroshi Yoneyama, Hideo Tamura, Electrochemical reactions concerned with electrochromism of polyaniline film-coated electrodes Journal of Electroanalytical Chemistry. ,vol. 177, pp. 281- 291 ,(1984) , 10.1016/0022-0728(84)80229-6
R.M.G. Rajapakse, L.P.P. Lankeshwara, M.A. Careem, Factors affecting the electropolymerization of aniline from aqueous solutions international conference on software maintenance. pp. 256- 256 ,(1994) , 10.1109/STSM.1994.835245
Eveline De Robertis*, Rodrigo S. Neves, Artur J. Motheo, Electropolymerization Studies of PAni/(poly)luminol Over Platinum Electrodes Molecular Crystals and Liquid Crystals. ,vol. 484, pp. 322- ,(2008) , 10.1080/15421400801904708
Loredana Vacareanu, Ana-Maria Catargiu, Mircea Grigoras, An Electrochemical Study of Two Self-Dopable Water-Soluble Aniline Derivatives: Electrochemical Deposition of Copolymers Journal of Automated Methods & Management in Chemistry. ,vol. 2012, pp. 737013- 737013 ,(2012) , 10.1155/2012/737013
Nuran Pekmez, Kadir Pekmez, Meral Arca, Attila Yildiz, None, The effect of monomer and acid concentrations on electrochemical polyaniline formation in acetonitrile Journal of Electroanalytical Chemistry. ,vol. 353, pp. 237- 246 ,(1993) , 10.1016/0022-0728(93)80300-7
Jia Li, Lanlan Liu, Di Zhang, Dian Yang, Jinbao Guo, Jie Wei, Fabrication of polyaniline/silver nanoparticles/multi-walled carbon nanotubes composites for flexible microelectronic circuits Synthetic Metals. ,vol. 192, pp. 15- 22 ,(2014) , 10.1016/J.SYNTHMET.2014.02.026
Paul DiMaggio, Bart Bonikowski, Make Money Surfing the Web? The Impact of Internet Use on the Earnings of U.S. Workers American Sociological Review. ,vol. 73, pp. 227- 250 ,(2008) , 10.1177/000312240807300203