Economical synthesis of composites of FeNi alloy nanoparticles evenly dispersed in two-dimensional reduced graphene oxide as thin and effective electromagnetic wave absorbers

作者: Juan Li , Dong Zhang , Hui Qi , Guangming Wang , Jimin Tang

DOI: 10.1039/C7RA13737K

关键词: Composite materialDielectricOxideReflection lossMicrowaveNanoparticleGrapheneMagnetic nanoparticlesAmorphous carbonMaterials science

摘要: Developing electromagnetic wave absorbing materials prepared by a facile and economical way is great challenge. Herein, we report feasible route to synthesize series of two-dimensional FeNi/rGO composites hydrothermal method followed carbonization process. The characterization confirms that nano-sized FeNi alloy nanoparticles are evenly supported onto graphene sheets without aggregation. homogeneous dispersion the may result from introduction glucose oxygen-containing groups on surface oxide. Measurements show microwave attenuation capability can be improved dramatically adjusting proportion dielectric magnetic components. Consequently, material (FeNi/rGO-100) exhibits an excellent absorption performance. In detail, minimum reflection loss −42.6 dB effective bandwidth 4.0 GHz reached with thinner thickness 1.5 mm. This study demonstrates synergistic effects among particles, reduced oxide amorphous carbon layers give rise highlighted ability. Overall, composite promising candidate used as absorber, has shown potential application construct multitudinous materials.

参考文章(57)
Shaoli Guo, Liuding Wang, Hongjing Wu, Facile synthesis and enhanced electromagnetic wave absorption of thorny-like Fe–Ni alloy/ordered mesoporous carbon composite Advanced Powder Technology. ,vol. 26, pp. 1250- 1255 ,(2015) , 10.1016/J.APT.2015.06.007
Biao Zhao, Bingbing Fan, Gang Shao, Wanyu Zhao, Rui Zhang, Facile Synthesis of Novel Heterostructure Based on SnO2 Nanorods Grown on Submicron Ni Walnut with Tunable Electromagnetic Wave Absorption Capabilities. ACS Applied Materials & Interfaces. ,vol. 7, pp. 18815- 18823 ,(2015) , 10.1021/ACSAMI.5B05482
Lina Wang, Xilai Jia, Yongfeng Li, Fan Yang, Liqiang Zhang, Liping Liu, Xiao Ren, Haitao Yang, Synthesis and microwave absorption property of flexible magnetic film based on graphene oxide/carbon nanotubes and Fe3O4 nanoparticles Journal of Materials Chemistry. ,vol. 2, pp. 14940- 14946 ,(2014) , 10.1039/C4TA02815E
Yuping Sun, Xianguo Liu, Chao Feng, Jincheng Fan, Yaohui Lv, Yiran Wang, Chengtao Li, A facile synthesis of FeNi3@C nanowires for electromagnetic wave absorber Journal of Alloys and Compounds. ,vol. 586, pp. 688- 692 ,(2014) , 10.1016/J.JALLCOM.2013.10.063
Meng Zong, Ying Huang, Yang Zhao, Xu Sun, Chunhao Qu, Didi Luo, Jiangbo Zheng, Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO–Fe3O4 composites RSC Advances. ,vol. 3, pp. 23638- 23648 ,(2013) , 10.1039/C3RA43359E
Bo Wen, Maosheng Cao, Mingming Lu, Wenqiang Cao, Honglong Shi, Jia Liu, Xixi Wang, Haibo Jin, Xiaoyong Fang, Wenzhong Wang, Jie Yuan, Reduced Graphene Oxides: Light-Weight and High-Efficiency Electromagnetic Interference Shielding at Elevated Temperatures Advanced Materials. ,vol. 26, pp. 3484- 3489 ,(2014) , 10.1002/ADMA.201400108
Meikang Han, Xiaowei Yin, Luo Kong, Mian Li, Wenyan Duan, Litong Zhang, Laifei Cheng, Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties Journal of Materials Chemistry. ,vol. 2, pp. 16403- 16409 ,(2014) , 10.1039/C4TA03033H
Luo Kong, Xiaowei Yin, Yajun Zhang, Xiaoyan Yuan, Quan Li, Fang Ye, Laifei Cheng, Litong Zhang, Electromagnetic Wave Absorption Properties of Reduced Graphene Oxide Modified by Maghemite Colloidal Nanoparticle Clusters Journal of Physical Chemistry C. ,vol. 117, pp. 19701- 19711 ,(2013) , 10.1021/JP4058498
Lei Zhao, Zhen-Bo Wang, Jia-Long Li, Jing-Jia Zhang, Xu-Lei Sui, Li-Mei Zhang, Hybrid of carbon-supported Pt nanoparticles and three dimensional graphene aerogel as high stable electrocatalyst for methanol electrooxidation Electrochimica Acta. ,vol. 189, pp. 175- 183 ,(2016) , 10.1016/J.ELECTACTA.2015.12.072