A novel shape-stabilized PEG/novolac resin by sol–gel polymerization
作者： Mina Nasiri , Ahmad Reza Bahramian , Hamidreza Hadizadeh Raeisi
DOI: 10.1007/S13726-016-0476-Y
关键词: Chemical engineering 、 Differential scanning calorimetry 、 Materials science 、 Crystallization 、 Polymerization 、 PEG ratio 、 Enthalpy 、 Fourier transform infrared spectroscopy 、 Crystallinity 、 Polyethylene glycol 、 Composite material
摘要: In this study, a novel polyethylene glycol (PEG)/novolac shape-stabilized, composite, phase-change material was prepared with various mass fractions of PEG via sol–gel polymerization. The influences content on morphology, crystallinity, enthalpy efficiency and shift melt temperature the materials (super cooling effect) were investigated. Fourier transform infrared spectroscopy indicated no chemical reaction during composite preparation showed O–H bonding intensity increased increase novolac content. Field emission scanning electron microscopy images shape-stabilized trapping chains into colloidal structure even at fraction as low 10 wt%. Differential calorimetry X-ray diffraction techniques revealed well thermal properties samples regarding compared to their bulk forms. Among in work, 15 wt% improved crystallinity neat PEG. This work not only supplied efficient without PCM leakage, but also new systems. system give opportunity have phase change crystallization behavior sample 85 comparison
springer.com
sci-hub.se 参考文章(15)
Meghdad Kamali Moghaddam, Sayed Majid Mortazavi, Taghi Khaymian, Micro/nano-encapsulation of a phase change material by coaxial electrospray method Iranian Polymer Journal. ,vol. 24, pp. 759- 774 ,(2015) , 10.1007/S13726-015-0364-X
Chongyun Wang, Lili Feng, Wei Li, Jie Zheng, Wenhuai Tian, Xingguo Li, Shape-stabilized phase change materials based on polyethylene glycol/porous carbon composite: The influence of the pore structure of the carbon materials Solar Energy Materials and Solar Cells. ,vol. 105, pp. 21- 26 ,(2012) , 10.1016/J.SOLMAT.2012.05.031
Ahmad Reza Bahramian, Leila Sadat Ahmadi, Mehrdad Kokabi, None, Performance evaluation of polymer/clay nanocomposite thermal protection systems based on polyethylene glycol phase change material Iranian Polymer Journal. ,vol. 23, pp. 163- 169 ,(2014) , 10.1007/S13726-013-0212-9
Yong Qian, Ping Wei, Pingkai Jiang, Zhi Li, Yonggang Yan, Kejian Ji, Weihua Deng, Preparation of shape-stabilized co-crystallized poly (ethylene glycol) composites as thermal energy storage materials Energy Conversion and Management. ,vol. 76, pp. 101- 108 ,(2013) , 10.1016/J.ENCONMAN.2013.07.014
Lili Feng, Jie Zheng, Huazhe Yang, Yanli Guo, Wei Li, Xingguo Li, Preparation and characterization of polyethylene glycol/active carbon composites as shape-stabilized phase change materials Solar Energy Materials and Solar Cells. ,vol. 95, pp. 644- 650 ,(2011) , 10.1016/J.SOLMAT.2010.09.033
C.Y. Zhao, G.H. Zhang, Review on microencapsulated phase change materials (MEPCMs): Fabrication, characterization and applications Renewable & Sustainable Energy Reviews. ,vol. 15, pp. 3813- 3832 ,(2011) , 10.1016/J.RSER.2011.07.019
Dong Zhang, Shengli Tian, Deyan Xiao, Experimental study on the phase change behavior of phase change material confined in pores Solar Energy. ,vol. 81, pp. 653- 660 ,(2007) , 10.1016/J.SOLENER.2006.08.010
Huazhe Yang, Lili Feng, Chongyun Wang, Wei Zhao, Xingguo Li, Confinement effect of SiO2 framework on phase change of PEG in shape-stabilized PEG/SiO2 composites European Polymer Journal. ,vol. 48, pp. 803- 810 ,(2012) , 10.1016/J.EURPOLYMJ.2012.01.016
Tingting Qian, Jinhong Li, Hongwen Ma, Jing Yang, The preparation of a green shape-stabilized composite phase change material of polyethylene glycol/SiO2 with enhanced thermal performance based on oil shale ash via temperature-assisted sol–gel method Solar Energy Materials and Solar Cells. ,vol. 132, pp. 29- 39 ,(2015) , 10.1016/J.SOLMAT.2014.08.017
Yuping Wu, Tao Wang, The dependence of phase change enthalpy on the pore structure and interfacial groups in hydrated salts/silica composites via sol-gel. Journal of Colloid and Interface Science. ,vol. 448, pp. 100- 105 ,(2015) , 10.1016/J.JCIS.2015.02.020