Uniform Field Re-entrant Cylindrical TE $$_{01\text {U}}$$ 01 U Cavity for Pulse Electron Paramagnetic Resonance Spectroscopy at Q-band

作者: Jason W. Sidabras , Edward J. Reijerse , Wolfgang Lubitz

DOI: 10.1007/S00723-017-0955-0

关键词: ResonatorExcitationMagnetic fieldSolid-state physicsAnalytical chemistryWaveguide (electromagnetism)Electron paramagnetic resonanceMicrowaveQ bandAtomic physicsChemistry

摘要: Uniform field (UF) resonators create a region-of-interest, where the sample volume receives homogeneous microwave magnetic ( $$B_1$$ ) excitation. However, as region-of-interest is increased, resonator efficiency reduced. In this work, new class of uniform introduced: re-entrant cylindrical TE $$_{\text {01U}}$$ cavity. Here, UF cavity designed with fins to increase overall match maximum typical $$_{011}$$ The for Q-band (34 GHz) and calculated have same electron paramagnetic resonance (EPR) signal intensity cavity, 60% in average $$\Lambda _\mathrm{ave}$$ over sample, has profile that 79.8% entire (98% region-of-interest). A H-type T-junction waveguide coupler inductive obstacles introduced increases dynamic range movable short while reducing frequency shift by 43% during over-coupling. assembly fabricated tested both on bench EPR experiments. This provides template improve spectroscopy pulse experiments at high frequencies.

参考文章(21)
Gunnar Jeschke, A. Schweiger, Principles of pulse electron paramagnetic resonance ,(2001)
Candice S. Klug, Jimmy B. Feix, Methods and applications of site-directed spin labeling EPR spectroscopy. Methods in Cell Biology. ,vol. 84, pp. 617- 658 ,(2008) , 10.1016/S0091-679X(07)84020-9
John R. Whinnery, Theodore Van Duzer, Simon Ramo, Fields and Waves in Communication Electronics ,(1966)
Wojciech Froncisz, Richard R. Mett, James S. Hyde, James R. Anderson, Cavity resonator for electron paramagnetic resonance spectroscopy having axially uniform field ,(2002)
Laxman Mainali, Jason W. Sidabras, Theodore G. Camenisch, Joseph J. Ratke, Marija Raguz, James S. Hyde, Witold K. Subczynski, Spin-label W-band EPR with seven-loop-six-gap resonator: Application to lens membranes derived from eyes of a single donor. Applied Magnetic Resonance. ,vol. 45, pp. 1343- 1358 ,(2014) , 10.1007/S00723-014-0578-7
James S. Hyde, Jason W. Sidabras, Richard R. Mett, Wojciech Froncisz, Theodore G. Camenisch, James R. Anderson, Multipurpose EPR loop-gap resonator and cylindrical TE011 cavity for aqueous samples at 94 GHz. Review of Scientific Instruments. ,vol. 78, pp. 034701- 034701 ,(2007) , 10.1063/1.2709746
James R. Anderson, Richard R. Mett, James S. Hyde, Cavities with axially uniform fields for use in electron paramagnetic resonance. II. Free space generalization Review of Scientific Instruments. ,vol. 73, pp. 3027- 3037 ,(2002) , 10.1063/1.1491032
Edward Reijerse, Friedhelm Lendzian, Roger Isaacson, Wolfgang Lubitz, A tunable general purpose Q-band resonator for CW and pulse EPR/ENDOR experiments with large sample access and optical excitation. Journal of Magnetic Resonance. ,vol. 214, pp. 237- 243 ,(2012) , 10.1016/J.JMR.2011.11.011
R. R. Mett, J. W. Sidabras, J. S. Hyde, Coupling of Waveguide and Resonator by Inductive and Capacitive Irises for EPR Spectroscopy Applied Magnetic Resonance. ,vol. 35, pp. 285- 318 ,(2009) , 10.1007/S00723-008-0162-0
James S. Hyde, Richard R. Mett, James R. Anderson, Cavities with axially uniform fields for use in electron paramagnetic resonance. III. Re-entrant geometries Review of Scientific Instruments. ,vol. 73, pp. 4003- 4009 ,(2002) , 10.1063/1.1510549