Functional superhydrophobic surfaces made of Janus micropillars

作者: Lena Mammen , Karina Bley , Periklis Papadopoulos , Frank Schellenberger , Noemí Encinas

DOI: 10.1039/C4SM02216E

关键词: PolymerMaterials scienceJanusFabricationWettingConfocal laser scanning microscopyBilayerAir cushionNanotechnologyMolecule

摘要: We demonstrate the fabrication of superhydrophobic surfaces consisting micropillars with hydrophobic sidewalls and hydrophilic tops, referred to as Janus micropillars. Therefore we first coat a micropillar array mono- or bilayer polymeric particles, merge particles together shield top faces while hydrophobizing walls. After removing polymer film, arrays can be selectively chemically functionalised groups. The remain even after functionalisation verified by laser scanning confocal microscopy. robustness behaviour proves that stability entrapped air cushion is determined forces acting at rim This insight should stimulate new way designing super liquid-repellent tunable liquid adhesion. In particular, combining superhydrophobicity protrusions groups may have exciting applications, including high-density microarrays for high-throughput screening bioactive molecules, cells, enzymes efficient water condensation. However, so far chemical attachment molecules has been accompanied complete wetting surface underneath. where post-functionalised retaining their properties, both promising challenging.

参考文章(57)
Daniel Bonn, Jens Eggers, Joseph Indekeu, Jacques Meunier, Etienne Rolley, Wetting and Spreading Reviews of Modern Physics. ,vol. 81, pp. 739- 805 ,(2009) , 10.1103/REVMODPHYS.81.739
Charles W. Extrand, Y. Kumagai, Liquid Drops on an Inclined Plane: The Relation between Contact Angles, Drop Shape, and Retentive Force joint international conference on information sciences. ,vol. 170, pp. 515- 521 ,(1995) , 10.1006/JCIS.1995.1130
Tanja Weil, Tom Vosch, Johan Hofkens, Kalina Peneva, Klaus Müllen, The Rylene Colorant Family—Tailored Nanoemitters for Photonics Research and Applications Angewandte Chemie. ,vol. 49, pp. 9068- 9093 ,(2010) , 10.1002/ANIE.200902532
Florian L. Geyer, Erica Ueda, Urban Liebel, Nicole Grau, Pavel A. Levkin, Superhydrophobic-superhydrophilic micropatterning: towards genome-on-a-chip cell microarrays. Angewandte Chemie. ,vol. 50, pp. 8424- 8427 ,(2011) , 10.1002/ANIE.201102545
Lena Mammen, Periklis Papadopoulos, Kathrin Friedemann, Stefanie Wanka, Daniel Crespy, Doris Vollmer, Hans-Jürgen Butt, Transparent and airtight silica nano- and microchannels with uniform tubular cross-section Soft Matter. ,vol. 9, pp. 9824- 9832 ,(2013) , 10.1039/C3SM51082D
A. B. D. Cassie, S. Baxter, Wettability of porous surfaces Transactions of The Faraday Society. ,vol. 40, pp. 546- 551 ,(1944) , 10.1039/TF9444000546
Lei Zhai, Michael C. Berg, Fevzi Ç. Cebeci, Yushan Kim, John M. Milwid, Michael F. Rubner, Robert E. Cohen, Patterned Superhydrophobic Surfaces:  Toward a Synthetic Mimic of the Namib Desert Beetle Nano Letters. ,vol. 6, pp. 1213- 1217 ,(2006) , 10.1021/NL060644Q
David Quéré, Wetting and Roughness Annual Review of Materials Research. ,vol. 38, pp. 71- 99 ,(2008) , 10.1146/ANNUREV.MATSCI.38.060407.132434
Junsheng S. Li, Erica Ueda, Asritha Nallapaneni, Linxian X. Li, Pavel A. Levkin, Printable superhydrophilic-superhydrophobic micropatterns based on supported lipid layers. Langmuir. ,vol. 28, pp. 8286- 8291 ,(2012) , 10.1021/LA3010932
Kyoo-Chul Park, Shreerang S Chhatre, Siddarth Srinivasan, Robert E Cohen, Gareth H McKinley, None, Optimal Design of Permeable Fiber Network Structures for Fog Harvesting Langmuir. ,vol. 29, pp. 13269- 13277 ,(2013) , 10.1021/LA402409F