Halloysite nanotubes as sustainable nanofiller for paper consolidation and protection

作者: Giuseppe Cavallaro , Giuseppe Lazzara , Stefana Milioto , Filippo Parisi

DOI: 10.1007/S10973-014-3865-5

关键词: HalloysiteConsolidation (soil)Ultimate tensile strengthMaterials scienceNanotubeComposite materialWettingCelluloseHydroxypropyl celluloseNanoparticle

摘要: We investigated the filling process of cellulose-based paper with natural clay nanotubes and their mixtures hydroxypropyl cellulose (HPC) that is commonly used as glue consolidant for degraded paper. A comprehensive characterization materials was carried out through morphology, wettability, thermal degradation, tensile properties. The treatment halloysite generated a decrease mechanical performance did not alter co-presence HPC nanoparticles more uniform distribution in fibrous structure significant enhancement both properties surface hydrophobicity respect to treatment. This work proposes use halloysite/HPC mixture new protocol consolidation represents starting point develop, biocompatible approach, smart composite material which nanotube cavity filled active species protection or response external stimuli.

参考文章(35)
N. F. F. Soares, F. K. V. Moreira, T. L. Fialho, N. R. Melo, Triclosan‐based antibacterial paper reinforced with nano‐montmorillonite: a model nanocomposite for the development of new active packaging Polymers for Advanced Technologies. ,vol. 23, pp. 901- 908 ,(2012) , 10.1002/PAT.1986
Mingxian Liu, Zhixin Jia, Fang Liu, Demin Jia, Baochun Guo, Tailoring the wettability of polypropylene surfaces with halloysite nanotubes joint international conference on information sciences. ,vol. 350, pp. 186- 193 ,(2010) , 10.1016/J.JCIS.2010.06.047
Elshad Abdullayev, Keita Sakakibara, Ken Okamoto, Wenbo Wei, Katsuhiko Ariga, Yuri Lvov, Natural Tubule Clay Template Synthesis of Silver Nanorods for Antibacterial Composite Coating ACS Applied Materials & Interfaces. ,vol. 3, pp. 4040- 4046 ,(2011) , 10.1021/AM200896D
Yuri M. Lvov, Dmitry G. Shchukin, Helmuth Möhwald, Ronald R. Price, Halloysite Clay Nanotubes for Controlled Release of Protective Agents ACS Nano. ,vol. 2, pp. 814- 820 ,(2008) , 10.1021/NN800259Q
Chengfeng Jin, Runshi Yan, Jianguo Huang, Cellulose substance with reversible photo-responsive wettability by surface modification Journal of Materials Chemistry. ,vol. 21, pp. 17519- 17525 ,(2011) , 10.1039/C1JM13399C
Yuri Lvov, Elshad Abdullayev, Functional polymer–clay nanotube composites with sustained release of chemical agents Progress in Polymer Science. ,vol. 38, pp. 1690- 1719 ,(2013) , 10.1016/J.PROGPOLYMSCI.2013.05.009
Luciana Sciascia, Maria Liria Turco Liveri, Marcello Merli, Kinetic and equilibrium studies for the adsorption of acid nucleic bases onto K10 montmorillonite Applied Clay Science. ,vol. 53, pp. 657- 668 ,(2011) , 10.1016/J.CLAY.2011.05.021
Celia Duce, Lisa Ghezzi, Massimo Onor, Ilaria Bonaduce, Maria Perla Colombini, Maria Rosaria Tine’, Emilia Bramanti, Physico-chemical characterization of protein–pigment interactions in tempera paint reconstructions: casein/cinnabar and albumin/cinnabar Analytical and Bioanalytical Chemistry. ,vol. 402, pp. 2183- 2193 ,(2012) , 10.1007/S00216-011-5684-X
Giuseppe Cavallaro, Giuseppe Lazzara, Stefana Milioto, Sustainable nanocomposites based on halloysite nanotubes and pectin/polyethylene glycol blend Polymer Degradation and Stability. ,vol. 98, pp. 2529- 2536 ,(2013) , 10.1016/J.POLYMDEGRADSTAB.2013.09.012