Near infra-red emission from a mer-Ru(II) complex: consequences of strong σ-donation from a neutral, flexible ligand with dual binding modes
作者： Amlan K. Pal , Nelsi Zaccheroni , Sebastiano Campagna , Garry S. Hanan
DOI: 10.1039/C3CC49880H
关键词: Ligand 、 Absorption spectroscopy 、 Charge (physics) 、 Crystallography 、 Near infra red 、 Bite angle 、 Stereochemistry 、 Tridentate ligand 、 Chelating ligands 、 Chemistry
摘要: A rare example of dual coordination modes by a novel tridentate ligand gives rise to unique fac-and mer-Ru(II/III) complexes. The mer-RuII-complex displays the farthest red-shift triplet metal-to-ligand charge transfer (3MLCT) emission with for mononuclear complex. This observation is consequence large bite angle and strong σ-donation ligand, combined effect which helps separate energy 3MLCT 3MC states.
rsc.org
sci-hub.se 参考文章(46)
Richard Eisenberg, Rethinking Water Splitting Science. ,vol. 324, pp. 44- 45 ,(2009) , 10.1126/SCIENCE.1172247
Jianhua Wang, Garry S. Hanan, Fr�d�rique Loiseau, Sebastiano Campagna, Prolonged luminescence lifetimes of Ru(II) complexes via the multichromophore approach: the excited-state storage element can be on a ligand not involved in the MLCT emitting state Chemical Communications. ,vol. 2004, pp. 2068- 2069 ,(2004) , 10.1039/B405619A
Glenn A. Crosby, James N. Demas, Measurement of photoluminescence quantum yields. Review The Journal of Physical Chemistry. ,vol. 75, pp. 991- 1024 ,(1971) , 10.1021/J100678A001
Rajesh Chakrabarty, Partha Sarathi Mukherjee, Peter J. Stang, Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles Chemical Reviews. ,vol. 111, pp. 6810- 6918 ,(2011) , 10.1021/CR200077M
Henk J. Bolink, Luca Cappelli, Eugenio Coronado, Michael Grätzel, Md. K. Nazeeruddin, Efficient and stable solid-state light-emitting electrochemical cell using tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) hexafluorophosphate. Journal of the American Chemical Society. ,vol. 128, pp. 46- 47 ,(2006) , 10.1021/JA0565065
Michael Jäger, Amanda Smeigh, Florian Lombeck, Helmar Görls, Jean-Paul Collin, Jean-Pierre Sauvage, Leif Hammarström, Olof Johansson, Cyclometalated RuII Complexes with Improved Octahedral Geometry: Synthesis and Photophysical Properties Inorganic Chemistry. ,vol. 49, pp. 374- 376 ,(2010) , 10.1021/IC9020788
Aloice O. Ogweno, Stephen O. Ojwach, Matthew P. Akerman, (Pyridyl)benzoazole ruthenium(II) and ruthenium(III) complexes: role of heteroatom and ancillary phosphine ligand in the transfer hydrogenation of ketones Dalton Transactions. ,vol. 43, pp. 1228- 1237 ,(2014) , 10.1039/C3DT51599K
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Broer. De Groot, Garry S. Hanan, Stephen J. Loeb, Dependence of complex structure on ligand conformation in palladium(II) complexes of the crown thioether ligands 2,5,8-trithia[9]-o-benzenophane (TT[9]OB) and 2,5,8-trithia[9]-m-benzenophane (TT[9]MB). Structures of PdCl2(TT[9]OB).cntdot.DMSO and PdCl2(TT[9]MB) Inorganic Chemistry. ,vol. 30, pp. 4644- 4647 ,(1991) , 10.1021/IC00024A036
Anthony Harriman, Annabelle Mayeux, Antoinette De Nicola, Raymond Ziessel, Synthesis and photophysical properties of ruthenium(II) bis(2,2′:6′,2″-terpyridine) complexes constructed from a diethynylated-thiophene residue Physical Chemistry Chemical Physics. ,vol. 4, pp. 2229- 2235 ,(2002) , 10.1039/B109966N