Doping strategy, properties and application of heteroatom-doped ordered mesoporous carbon

作者: Guozhao Ji , Aimin Li , Yuan Gao , Qing Wang , Jiamin Niu

DOI: 10.1039/D0RA08993A

关键词: NanotechnologyMaterials scienceHeteroatomBoronChemical vapor depositionSupercapacitorSurface modificationDopingElectrocatalystElectrochemistry

摘要: To date, tremendous achievements have been made to produce ordered mesoporous carbon (OMC) with well-designed and controllable porous structure for catalysis, energy storage conversion. However, OMC as electrode material suffers from poor hydrophilicity weak electrical conductivity. Numerous attempts much research interest devoted dope different heteroatoms in the defects enhance its performance, such nitrogen, phosphorus, sulphur, boron, multi heteroatoms. Unfortunately, “how–why–what” question heteroatom-doped has not summarized any published reports. Therefore, this review focuses on functionalization strategies of corresponding process characteristics, including situ method, post treatment chemical vapor deposition. The fundamentally influencing mechanisms various electrochemical property are detail. Furthermore, provides an updated summary about applications supercapacitor, electrocatalysis, ion battery during last decade. Finally, future challenges also proposed.

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