Single-site catalysts for olefin polymerization
作者： John A. Tyrell , Bradley P. Etherton , Sandor Nagy , Ramesh Krishnamurti
DOI:
关键词: Polymer chemistry 、 Organic chemistry 、 Lanthanide 、 Catalysis 、 Olefin polymerization 、 Aryl 、 Chemistry 、 Post-metallocene catalyst 、 Single site 、 Metal
摘要: A single-site olefin polymerization catalyst and method of making it are disclosed. The comprises an activator organometallic complex. complex a Group 3 to 10 transition or lanthanide metal, M, at least one indenoindolyl ligand that is π-bonded M. key made in two steps from readily available indanones aryl hydrazines. Reaction its anion with source the metal completes remarkably simple synthetic route new family catalysts.
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