Preparation of triphenylphosphine
作者： Dieter Hermeling , Hardo Siegel , Peter Lechtken , Randolf Hugo , Peter Bassler
DOI:
关键词: Hydrogen chloride 、 Sulfuryl chloride 、 Diphosgene 、 Phosphorus trichloride 、 Nuclear chemistry 、 Thionyl chloride 、 Chlorine 、 Triphenylphosphine dichloride 、 Chemistry 、 Inorganic chemistry 、 Triphenylphosphine
摘要: Triphenylphosphine (TPP) is prepared by reacting triphenylphosphine dichloride (TPPCl2) with magnesium, aluminum and/or iron in the presence of an inert solvent, employing a TPPCl2 solution whose content phosgene, chlorine, diphosgene, hydrogen chloride, thionyl sulfuryl phosphorus trichloride, oxychloride aliphatic halogen compounds (active chlorine compounds) totals less than 1000 ppm Cl.
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