Zur selektiven Bestimmung spezifischer Metalloberflächen
作者： H. L. Gruber , A. Hausen
DOI: 10.1007/BF01553117
关键词: Chemistry 、 Medicinal chemistry 、 Physical and Theoretical Chemistry 、 Colloid and Surface Chemistry 、 Materials Chemistry 、 Polymers and Plastics
摘要: Der Dispersionsgrad der metallischen Phase bzw. die spezifische Metalloberflache von Metall-Trager-Katalysatoren mit sehr kleinen Metallkonzentrationen kann durch Messung Chemisorption Wasserstoff oder Kohlenmonoxid bestimmt werden. Methodik und Problematik solcher Chemisorptionsmessungen werden speziell fur Platinkatalysatoren ausfuhrlich diskutiert.
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sci-hub.se 参考文章(35)
P. W. Selwood, Adsorption and collective paramagnetism ,(1962)
H. L. Gruber, An Adsorption Flow Method for Specific Metal Surface Area Determination. Analytical Chemistry. ,vol. 34, pp. 1828- 1831 ,(1962) , 10.1021/AC60193A045
A. S. JOY, T. A. DORLING, Influence of a Chemisorbed Film on Subsequent Physical Adsorption Processes Nature. ,vol. 168, pp. 433- 434 ,(1951) , 10.1038/168433A0
T DORLING, R MOSS, The structure and activity of supported metal catalystsI. Crystallite size and specific activity for benzene hydrogenation of platinum/silica catalysts Journal of Catalysis. ,vol. 5, pp. 111- 115 ,(1966) , 10.1016/S0021-9517(66)80130-6
H. W. Kohn, M. Boudart, Reaction of Hydrogen with Oxygen Adsorbed on a Platinum Catalyst. Science. ,vol. 145, pp. 149- 150 ,(1964) , 10.1126/SCIENCE.145.3628.149
R. L. Gale, R. A. Beebe, Determination of Heats of Adsorption on Carbon Blacks and Bone Mineral by Chromatography Using the Eluted Pulse Technique The Journal of Physical Chemistry. ,vol. 68, pp. 555- 567 ,(1964) , 10.1021/J100785A020
F. H. Pollard, The Adsorption of Carbon Monoxide and Hydrogen by Platinized Asbestos The Journal of Physical Chemistry. ,vol. 27, pp. 356- 375 ,(1922) , 10.1021/J150229A005
Lawrence Spenadel, Michel Boudart, DISPERSION OF PLATINUM ON SUPPORTED CATALYSTS The Journal of Physical Chemistry. ,vol. 64, pp. 204- 207 ,(1960) , 10.1021/J100831A004
J BENSON, Hydrogen-oxygen titration method for the measurement of supported palladium surface areas Journal of Catalysis. ,vol. 4, pp. 704- 710 ,(1965) , 10.1016/0021-9517(65)90271-X
F. S. STONE, P. F. TILEY, Influence of a Chemisorbed Film on Subsequent Physical Adsorption Processes on Solids Nature. ,vol. 167, pp. 654- 655 ,(1951) , 10.1038/167654A0