Hydrogen-atom abstraction from methanol by hydroxyl radical

作者: Wayne P. Hess , Frank P. Tully

DOI: 10.1021/J100342A049

关键词: ChemistryPrimary alcoholDeuteriumKinetic isotope effectReaction rate constantPhotochemistryHydrogen atom abstractionCrystallographyBranching fractionChemical kineticsArrhenius equation

摘要: … radical (V).20 Our value of 4.8 for the pKa of 1,6-dihydroxy-2,4,5-trichlorocyclohexadienyl radical seems reasonable in light of the further stabilization conferred on the radical anion by …

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