Bronsted-Evans-Polanyi relation of multistep reactions and volcano curve in heterogeneous catalysis
作者： Jun Cheng , P. Hu , Peter Ellis , Sam French , Gordon Kelly
DOI: 10.1021/JP711191J
关键词: Thermodynamics 、 Heterogeneous catalysis 、 Dissociation (chemistry) 、 Catalysis 、 Chemistry 、 Adsorption 、 Ammonia production 、 Desorption 、 Organic chemistry 、 Density functional theory 、 Dehydrogenation
摘要: Multistep surface processes involving a number of association reactions and desorption may be considered as hypothetical one-step processes. Thus, heterogeneous catalytic can treated kinetically consisting two steps: adsorption desorption. It is also illustrated that the process follows BEP relation. A volcano curve obtained from kinetic analysis by including both
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