Aragonite Nanorod Arrays through Molecular Controlled Growth on Single-Crystalline Substrate and Polysaccharide Surface

作者: Monami Suzuki , Yuya Oaki , Hiroaki Imai

DOI: 10.1021/ACS.CGD.6B00237

关键词: NucleationNanorodSupersaturationChitosanAnhydrousAragoniteMaterials scienceCrystallographyPolymorphism (materials science)Crystal growth

摘要: We produced bunched aragonite nanorods through crystal growth controlled by an acidic polysaccharide, alginate, in a supersaturated solution. The highly ordered arrays of c-axis-elongated ∼100 nm diameter were grown on the (001) surface single-crystalline substrate with specific adsorption soluble polysaccharide. Freestanding films consisting obtained using insoluble anhydrous chitosan, as template for nucleation metastable phase. orientation rods was improved repetition growth. Parallel control polymorphism, orientation, and morphology molecular provides biomimetic hierarchical architectures calcium carbonate crystals.

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