The Free Energy of Hydration of Gaseous Ions, and the Absolute Potential of the Normal Calomel Electrode
作者： Wendell M. Latimer , Kenneth S. Pitzer , Cyril M. Slansky
DOI: 10.1063/1.1750387
关键词: Born equation 、 Atomic physics 、 Dielectric 、 Halide 、 Crystal 、 Alkali metal 、 Chemistry 、 Saturated calomel electrode 、 Ion 、 Absolute electrode potential
摘要: The free energies of hydration the alkali and halide ions are found to agree reasonably well with simple expression Born (—ΔF=(1–1/D)Ne2/2re) for solution charged spheres in a dielectric medium, provided crystal radii suitably modified so as correspond cavities medium. results show that constant water remains large even intense field next ion. entropies also be consistent these radii. Because simplicity this calculation, resulting individual considered priori most probable used calculate value —0.50 volt absolute potential calomel half‐cell.
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sci-hub.se 参考文章(10)
C. B. Kazda, The Photo-Electric Threshold for Mercury Physical Review. ,vol. 26, pp. 643- 654 ,(1925) , 10.1103/PHYSREV.26.643
W. J. Dunning, W. J. Shutt, The dielectric properties of aqueous solutions of salts Transactions of The Faraday Society. ,vol. 34, pp. 467- 479 ,(1938) , 10.1039/TF9383400467
Wendell M. Latimer, The Entropy of Aqueous Ions and the Nature of the Entropy of Hydration. Chemical Reviews. ,vol. 18, pp. 349- 358 ,(1936) , 10.1021/CR60060A007
J. D. Bernal, R. H. Fowler, A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions The Journal of Chemical Physics. ,vol. 1, pp. 515- 548 ,(1933) , 10.1063/1.1749327
Andr. Voet, Ionic radii and heat of hydration Transactions of The Faraday Society. ,vol. 32, pp. 1301- 1304 ,(1936) , 10.1039/TF9363201301
T. J. Webb, THE FREE ENERGY OF HYDRATION OF IONS AND THE ELECTROSTRICTION OF THE SOLVENT Journal of the American Chemical Society. ,vol. 48, pp. 2589- 2603 ,(1926) , 10.1021/JA01421A013
Wendell M. Latimer, Kenneth S. Pitzer, Wendell V. Smith, The Entropies of Aqueous Ions Journal of the American Chemical Society. ,vol. 60, pp. 1829- 1831 ,(1938) , 10.1021/JA01275A034
Linus Pauling, THE SIZES OF IONS AND THE STRUCTURE OF IONIC CRYSTALS Journal of the American Chemical Society. ,vol. 49, pp. 765- 790 ,(1927) , 10.1021/JA01402A019
Allen Garrison, A DETERMINATION OF ABSOLUTE SINGLE ELECTRODE POTENTIALS Journal of the American Chemical Society. ,vol. 45, pp. 37- 44 ,(1923) , 10.1021/JA01654A005
Maurice L. Huggins, Lattice Energies, Equilibrium Distances, Compressibilities and Characteristic Frequencies of Alkali Halide Crystals The Journal of Chemical Physics. ,vol. 5, pp. 143- 148 ,(1937) , 10.1063/1.1749993