Catalytic transformations of cellulose and cellulose-derived carbohydrates into organic acids

作者: Weiping Deng , Qinghong Zhang , Ye Wang

DOI: 10.1016/J.CATTOD.2013.12.041

关键词: BifunctionalCelluloseLevulinic acidAcetic acidFormic acidChemistryGluconic acidOrganic chemistryLignocellulosic biomassHydrolysis

摘要: Abstract The efficient utilization of lignocellulosic biomass for the production chemicals and fuels is high significance from viewpoint establishing sustainable society. selective transformation cellulose, main component biomass, into platform chemicals, which can be easily converted to various or in subsequent step, under mild conditions a promising route. Organic acids such as levulinic acid, lactic gluconic formic acid are important conversion carbohydrates organic has attracted much attention recent years. present short review article highlights research progress development new routes cellulose cellulose-derived carbohydrates. In particular, we will demonstrate that bifunctional catalysts coupling sites activation glycosidic bonds via hydrolysis metal nanoparticles oxidation glucose intermediate show performances water presence O2. multifunctional catalytic systems combining abilities isomerization dehydration–rehydration retro-aldol fragmentation provide anaerobic conditions. reaction mechanism each case also discussed gain insights how C O activated cleaved roles these steps.

参考文章(106)
Jizhe Zhang, Xin Liu, Mohamed Nejib Hedhili, Yihan Zhu, Yu Han, None, Highly Selective and Complete Conversion of Cellobiose to Gluconic Acid over Au/Cs2HPW12O40 Nanocomposite Catalyst Chemcatchem. ,vol. 3, pp. 1294- 1298 ,(2011) , 10.1002/CCTC.201100106
Yi‐Heng Percival Zhang, Lee R Lynd, None, Toward an aggregated understanding of enzymatic hydrolysis of cellulose: noncomplexed cellulase systems. Biotechnology and Bioengineering. ,vol. 88, pp. 797- 824 ,(2004) , 10.1002/BIT.20282
Dieter Klemm, Brigitte Heublein, Hans-Peter Fink, Andreas Bohn, Cellulose: Fascinating Biopolymer and Sustainable Raw Material Angewandte Chemie. ,vol. 44, pp. 3358- 3393 ,(2005) , 10.1002/ANIE.200460587
Chun-Hui Zhou, Xi Xia, Chun-Xiang Lin, Dong-Shen Tong, Jorge Beltramini, Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels Chemical Society Reviews. ,vol. 40, pp. 5588- 5617 ,(2011) , 10.1039/C1CS15124J
Stijn Van de Vyver, Joice Thomas, Jan Geboers, Stefaan Keyzer, Mario Smet, Wim Dehaen, Pierre A. Jacobs, Bert F. Sels, Catalytic production of levulinic acid from cellulose and other biomass-derived carbohydrates with sulfonated hyperbranched poly(arylene oxindole)s Energy and Environmental Science. ,vol. 4, pp. 3601- 3610 ,(2011) , 10.1039/C1EE01418H
B. Girisuta, L. P. B. M. Janssen, H. J. Heeres, Kinetic study on the acid-catalyzed hydrolysis of cellulose to levulinic acid Industrial & Engineering Chemistry Research. ,vol. 46, pp. 1696- 1708 ,(2007) , 10.1021/IE061186Z
M. Weber, J.‐T. Wang, S. Wasmus, R. F. Savinell, Formic Acid Oxidation in a Polymer Electrolyte Fuel Cell A Real‐Time Mass‐Spectrometry Study Journal of The Electrochemical Society. ,vol. 143, ,(1996) , 10.1149/1.1836961
Juben N. Chheda, George W. Huber, James A. Dumesic, Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals. Angewandte Chemie. ,vol. 46, pp. 7164- 7183 ,(2007) , 10.1002/ANIE.200604274
Jiping Ma, Zhongtian Du, Jie Xu, Qinghui Chu, Yi Pang, Efficient Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Diformylfuran, and Synthesis of a Fluorescent Material Chemsuschem. ,vol. 4, pp. 51- 54 ,(2011) , 10.1002/CSSC.201000273
Stijn Van de Vyver, Jan Geboers, Pierre A. Jacobs, Bert F. Sels, Recent Advances in the Catalytic Conversion of Cellulose Chemcatchem. ,vol. 3, pp. 82- 94 ,(2011) , 10.1002/CCTC.201000302