Function of metal oxide and complex oxide catalysts for hydrocracking of coal

作者: K. Tanabe , H. Hattori , T. Yamaguchi , T. Iizuka , H. Matsuhashi

DOI: 10.1016/0378-3820(86)90026-3

关键词: Inorganic chemistryCatalysisCoalCobaltLiquefactionChemistryBituminous coalDiphenylmethaneCatalyst supportOxide

摘要: Abstract The catalytic activity and selectivity of metal oxides complex for the liquefaction bituminous coal lignite are reviewed first discussed in connection with surface properties catalysts. However, it has been realized that functions catalysts not fully understood. Thus, present work, hydrocracking diphenylmethane, diphenyl ether, benzyl phenyl ether as model compounds coal, dehydration 2-propanol a test reaction cracking ability (acidity) catalyst, hydrogenation naphthalene catalyst were studied by employing various oxide It concluded acidic property plays an important role CC bond cleavage, while is CO cleavage. This conclusion was found to be agreement results Akabira (carbon content: 83.0%) Big Brown 72.3%). That is, highly exhibited high activities coals carbon content, whereas possessing showed containing large amount oxygen. best three MoO 3 Fe 2 O SnO , TiO Fe SO 4 2- whose almost comparable well known CoOAl though they did contain expensive cobalt. For lignite, among

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