Systematic trends in the vibrational frequency shifts of some molecules trapped in amorphous water ice

作者: A.A Vigasin , L Schriver-Mazzuoli , A Schriver

DOI: 10.1016/S0022-2860(03)00460-5

关键词: Infrared spectroscopySpectroscopyAnalytical chemistryAtmosphereAbsorption (chemistry)Molecular vibrationChemistryIntermolecular forceAmorphous solidMoleculeChemical physics

摘要: This paper focuses on systematic examination of the vibrational frequency shifts some molecules trapped in water ices. It is shown that for bands, which laboratory taken data are available, magnitude and sign a shift ice can be approximately predicted using empirical correlations with macroscopic properties host. These results useful identification carriers absorption matrix spectroscopy, study intermolecular interactions, number applications involving remote spectroscopic sensing molecular species atmosphere space.

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