Dynamic study of several fluorinated U(IV) β-diketonates in solutions
作者： Dominique Martin-Rovet , Gérard Folcher , Catherine Kiener
DOI: 10.1016/0022-1902(81)80022-X
关键词: Intramolecular force 、 Analytical chemistry 、 19f nmr spectroscopy 、 Ligand 、 Proton NMR 、 Chemistry 、 Physical chemistry
摘要: Abstract The 19F NMR spectroscopy of several fluorinated β-diketonates U(IV), where the ligand chosen is asymmetrical, has been studied as a function temperature. complexes are U(FOD)4, U(TFBA)4 and U(TFAA)4. Intramolecular motions observed their freezing occurs near −90°C. data in agreement with those 1H NMR.
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