A nickel complex of a conjugated bis-dithiocarbazate Schiff base for the photocatalytic production of hydrogen.
作者： Catherine F. Wise , Dan Liu , Kathryn J. Mayer , Patrick M. Crossland , Carolyn L. Hartley
DOI: 10.1039/C5DT02042E
关键词: Hydrogen 、 Schiff base 、 Photochemistry 、 Triethylamine 、 Photocatalysis 、 Nickel 、 Chemistry 、 Catalysis 、 Hydrogen production 、 Electrocatalyst
摘要: We report a nickel complex containing conjugated bis-dithiocarbazate ligand that is an active catalyst for the reduction of protons into hydrogen gas. Light-driven generation observed from system this molecular coupled with fluorescein photosensitizer and triethylamine sacrificial donor. The photocatalytic stable over 70 hours, achieving 3300 turnovers respect to catalyst. also electrocatalyst proton catalysis occurring at −1.7 V vs. Fc+/Fc. represents highly generation.
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