Structures in Langmuir-Blodgett Films of Amphiphilic Tetrathiafulvalenes and Tetrafluorotetracyanoquinodimethane CT Complex
作者： Yoko Tatewaki , Shuji Okada , Junko Takizawa , Tatsuya Hatanaka , Mutsumi Kimura
DOI: 10.1080/15421401003613584
关键词: Crystallography 、 Nanowire 、 Chirality (chemistry) 、 Langmuir–Blodgett film 、 Thin film 、 Hydrogen bond 、 Nanotechnology 、 Deposition (law) 、 Mica 、 Nanostructure 、 Materials science
摘要: An asymmetric TTF derivative 1 having two arms substituted by amide and chiral groups was synthesized its CT complex with 2,3,5,6-tetrafluoro-7,7′,8,8′-tetracyano-p-quinodimethane (1-F4TCNQ) were also prepared. Thin film formation at the air-water interface deposition on substrates of 1-F4TCNQ investigated. When we deposited prepared pure water onto a mica surface single upstroke withdrawal, curved nanowire structures observed thin films. On contrary, without F4TCNQ showed three-dimensional dome films, morphologies Langmuir-Blodgett (LB) films depended existence F4TCNQ. average dimension 6.0 (height) × 500 (width) × 10000 (length) nm3.
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