Metalmetal bonded rutheniummanganese complexes: an unexpected phosphido-bridged complex
作者： Sylviane Sabo , Bruno Chaudret , Daniele Gervais
DOI: 10.1016/0022-328X(83)89519-9
关键词: Medicinal chemistry 、 Hydride 、 Ionic bonding 、 Triphenylphosphine 、 Photochemistry 、 Chemistry
摘要: Abstract Reactions of NaMn(CO)3 with RuCl2(PMe3)4, RuCl2(dppm)2 and RuCl2(PPh3)3 lead either to an ionic species [Ru2Cl3(PMe3)6]+[Mn(CO)5]− or metal—metal bonded RuMn compounds such as RuMn(μ-CO)2(CO)3(μ-dppm)2 Cl, and, quite unexpectedly, the μ-phosphido complex RuMn(μ-PPh2)(CO)6(PPh3)2 via a hydride intermediate.
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