Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1 H -benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands
作者： G.-F. Wang , X. Zhang , S.-W. Sun , Q.-P. Han , X. Yang
DOI: 10.1134/S1063774515070305
关键词: Oxygen 、 Crystallography 、 Infrared spectroscopy 、 Chemistry 、 X-ray crystallography 、 Coordination polymer 、 Crystal structure 、 Ion 、 Octahedral molecular geometry 、 Absorption spectroscopy
摘要: 3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L 1 , 1) and its Mn(II) complex, [Mn(L )2(SCN)2]∞ (2), were synthesized characterized by elemental analyses, IR spectroscopy single-crystal X-ray diffraction. The ion in 2 is six-coordinated to four nitrogen atoms of two L ligands, SCN-ligands, oxygen other ligands form a distorted octahedral geometry. Therefore, each links Mn ions through the O N generate 2D sheet structure.
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