Understanding Membrane Failure in PEMFC: Comparison of Diagnostic Tools at Different Observation Scales

作者: G. De Moor , C. Bas , N. Charvin , E. Moukheiber , F. Niepceron

DOI: 10.1002/FUCE.201100161

关键词: Proton exchange membrane fuel cellNuclear engineeringFuel cellsStack (abstract data type)Membrane electrode assemblyDiagnostic toolsSingle stepThermographyAnalytical chemistryMembraneMaterials science

摘要: Polyelectrolyte membrane used in proton exchange fuel cell (PEMFC) should act as a barrier to hydrogen and electrons. In the present work, fast robust specific tools were developed both characterize these properties localize defects, such pinholes or short-circuits, within electrode assembly (MEA). The identification of defective cells without disassembling Axane's stack was performed single step through passive electrical technique so-called “relaxometry” by internal gas leak measurements. flaws further tracked inside MEA using Infrared Thermography order obtain their precise location. latter, after disassembly, permitted reveal defects responsible for Fuel Cell shutdown. A third dealt with SEM examinations identify origin nature failure.

参考文章(41)
Jinfeng Wu, Xiao-Zi Yuan, Jonathan J. Martin, Haijiang Wang, Daijun Yang, Jinli Qiao, Jianxin Ma, Proton exchange membrane fuel cell degradation under close to open-circuit conditions Journal of Power Sources. ,vol. 195, pp. 1171- 1176 ,(2010) , 10.1016/J.JPOWSOUR.2009.08.095
Matthew M. Mench, T. Nejat Veziroğlu, Emin Caglan Kumbur, Polymer electrolyte fuel cell degradation Academic Press is an imprint of Elsevier. ,(2012)
Zongwen Lu, Changsik Kim, Anette M. Karlsson, James C. Cross, Michael H. Santare, Effect of gas diffusion layer modulus and land–groove geometry on membrane stresses in proton exchange membrane fuel cells Journal of Power Sources. ,vol. 196, pp. 4646- 4654 ,(2011) , 10.1016/J.JPOWSOUR.2011.01.028
J. Stumper, R. Rahmani, F. Fuss, Open circuit voltage profiling as diagnostic tool during stack lifetime testing Journal of Power Sources. ,vol. 195, pp. 4928- 4934 ,(2010) , 10.1016/J.JPOWSOUR.2009.12.061
Ruiliang Jia, Binghong Han, Kemal Levi, Takuya Hasegawa, Jiping Ye, Reinhold H. Dauskardt, Effect of cation contamination and hydrated pressure loading on the mechanical properties of proton exchange membranes Journal of Power Sources. ,vol. 196, pp. 3803- 3809 ,(2011) , 10.1016/J.JPOWSOUR.2010.12.066
Yaliang Tang, Ahmet Kusoglu, Anette M. Karlsson, Michael H. Santare, Simon Cleghorn, William B. Johnson, Mechanical properties of a reinforced composite polymer electrolyte membrane and its simulated performance in PEM fuel cells Journal of Power Sources. ,vol. 175, pp. 817- 825 ,(2008) , 10.1016/J.JPOWSOUR.2007.09.093
Yongqiang Li, Jennifer K. Quincy, Scott W. Case, Michael W. Ellis, David A. Dillard, Yeh-Hung Lai, Michael K. Budinski, Craig S. Gittleman, Characterizing the fracture resistance of proton exchange membranes Journal of Power Sources. ,vol. 185, pp. 374- 380 ,(2008) , 10.1016/J.JPOWSOUR.2008.06.056
M. Miller, A. Bazylak, A review of polymer electrolyte membrane fuel cell stack testing Journal of Power Sources. ,vol. 196, pp. 601- 613 ,(2011) , 10.1016/J.JPOWSOUR.2010.07.072
Minoru Inaba, Taro Kinumoto, Masayuki Kiriake, Ryota Umebayashi, Akimasa Tasaka, Zempachi Ogumi, Gas crossover and membrane degradation in polymer electrolyte fuel cells Electrochimica Acta. ,vol. 51, pp. 5746- 5753 ,(2006) , 10.1016/J.ELECTACTA.2006.03.008
T.T. Aindow, J. O’Neill, Use of mechanical tests to predict durability of polymer fuel cell membranes under humidity cycling Journal of Power Sources. ,vol. 196, pp. 3851- 3854 ,(2011) , 10.1016/J.JPOWSOUR.2010.12.031