Palladium-Mediated Ethylation of the Imidazolium Cation Monitored In Operando on a Solid Catalyst with Ionic Liquid Layer
作者： Tanja Bauer , Veit Hager , Marc B. Williams , Mathias Laurin , Tibor Döpper
关键词: Ionic liquid 、 Palladium 、 Diffuse reflection 、 Reaction mechanism 、 Moiety 、 Nuclear magnetic resonance spectroscopy 、 Chemistry 、 Heterogeneous catalysis 、 Catalysis 、 Inorganic chemistry
摘要: The ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate [EMIM][EtOSO3] was supported on Pd-Al2O3 to yield a solid catalyst with layer (SCILL) material. During the hydrogenation of ethene, it found that ethene incorporated into imidazolium moiety in reaction catalyzed by palladium surface. formation 1,2-diethyl-3-methylimidazolium confirmed ex situ means NMR spectroscopy. Moreover, itself could be monitored in situ diffuse reflection infrared Fourier transformation (DRIFT) A mechanism involving surface carbene species proposed basis analytical data.
sci-hub.se 参考文章(40)
M.H. Valkenberg, C. deCastro, W.F. Hölderich, Immobilisation of chloroaluminate ionic liquids on silica materials Topics in Catalysis. ,vol. 14, pp. 139- 144 ,(2000) , 10.1023/A:1009023520210
Reinout Meijboom, Marco Haumann, Thomas E Müller, Normen Szesni, None, Synthetic Methodologies for Supported Ionic Liquid Materials Supported Ionic Liquids: Fundamentals and Applications. pp. 75- 94 ,(2014) , 10.1002/9783527654789.CH4
Päivi Mäki-Arvela, Jyri-Pekka Mikkola, Pasi Virtanen, Eero Salminen, Selective Hydrogenation for Fine Chemical Synthesis Wiley-VCH Verlagsgesellschaft. pp. 251- 262 ,(2014) , 10.1002/9783527654789.CH12
Yu Sung Chun, Ju Yeon Shin, Choong Eui Song, Sang-gi Lee, Palladium nanoparticles supported onto ionic carbon nanotubes as robust recyclable catalysts in an ionic liquid. Chemical Communications. pp. 942- 944 ,(2008) , 10.1039/B715463A
Swetlana Schauermann, Jens Hoffmann, Viktor Johánek, Jens Hartmann, Jörg Libuda, Hans-Joachim Freund, Katalytische Aktivität und Vergiftung spezifischer aktiver Zentren von Metall-Nanopartikeln auf Trägern† Angewandte Chemie. ,vol. 114, pp. 2643- 2646 ,(2002) , 10.1002/1521-3757(20020715)114:14<2643::AID-ANGE2643>3.0.CO;2-S
J. Joni, M. Haumann, P. Wasserscheid, Development of a Supported Ionic Liquid Phase (SILP) Catalyst for Slurry‐Phase Friedel–Crafts Alkylations of Cumene Advanced Synthesis & Catalysis. ,vol. 351, pp. 423- 431 ,(2009) , 10.1002/ADSC.200800672
Swetlana Schauermann, Jens Hoffmann, Viktor Johánek, Jens Hartmann, Jörg Libuda, Hans-Joachim Freund, Catalytic Activity and Poisoning of Specific Sites on Supported Metal Nanoparticles Angewandte Chemie International Edition. ,vol. 41, pp. 2532- 2535 ,(2002) , 10.1002/1521-3773(20020715)41:14<2532::AID-ANIE2532>3.0.CO;2-3
Yanlong Gu, Guangxing Li, Ionic Liquids‐Based Catalysis with Solids: State of the Art Advanced Synthesis & Catalysis. ,vol. 351, pp. 817- 847 ,(2009) , 10.1002/ADSC.200900043
Christian P. Mehnert, Raymond A. Cook, Nicholas C. Dispenziere, Mobae Afeworki, Supported ionic liquid catalysis--a new concept for homogeneous hydroformylation catalysis. Journal of the American Chemical Society. ,vol. 124, pp. 12932- 12933 ,(2002) , 10.1021/JA0279242
C. DeCastro, E. Sauvage, M.H. Valkenberg, W.F. Hölderich, Immobilised Ionic Liquids as Lewis Acid Catalysts for the Alkylation of Aromatic Compounds with Dodecene Journal of Catalysis. ,vol. 196, pp. 86- 94 ,(2000) , 10.1006/JCAT.2000.3004