Optical properties of electrochromic vanadium pentoxide
作者： Stuart F. Cogan , Nguyet M. Nguyen , Stephen J. Perrotti , R. David Rauh
DOI: 10.1063/1.344432
关键词: Inorganic chemistry 、 Absorption (electromagnetic radiation) 、 Infrared spectroscopy 、 Absorbance 、 Analytical chemistry 、 Absorption edge 、 Electrochromism 、 Vanadium 、 Pentoxide 、 Lithium 、 Chemistry
摘要: Electrochemical and spectroscopic measurements were used to characterize the electrochromic behavior of sputtered V2O5 films. In response to lithium intercalation, the fundamental optical absorption edge of V2O5 shifts to high energies by 0.20–0.31 eV as the lithium concentration increases from Li0. 0V2O5 to Li0. 86V2O5. There is a corresponding increase in the near‐infrared absorption that exhibits Beer's law behavior at low lithium concentrations. The shift in absorption edge results in a large decrease in absorbance in the …
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J. S. E. M. Svensson, C. G. Granqvist, No visible electrochromism in high-quality e-beam evaporated In(2)O(3):Sn films. Applied Optics. ,vol. 24, pp. 2284- 2285 ,(1985) , 10.1364/AO.24.002284
S.F. Cogan, T.D. Plante, R.S. McFadden, R.D. Rauh, Solar modulation in a-WO3/a-IrO2 and c-KxWO3+(x/2)/a-IrO2 complementary electrochromic windows Solar Energy Materials. ,vol. 16, pp. 371- 382 ,(1987) , 10.1016/0165-1633(87)90031-1
Yoshitaka Fujita, Katsuhiro Miyazaki, Chiei Tatsuyama, On the Electrochromism of Evaporated V2O5Films Japanese Journal of Applied Physics. ,vol. 24, pp. 1082- 1086 ,(1985) , 10.1143/JJAP.24.1082
S. Hub, A. Tranchant, R. Messina, X-ray investigations on electroformed LixV2O5 bronzes Electrochimica Acta. ,vol. 33, pp. 997- 1002 ,(1988) , 10.1016/0013-4686(88)80101-4
Z. M. Jarzebski, Preparation and physical properties of transparent conducting oxide films physica status solidi (a). ,vol. 71, pp. 13- 41 ,(1982) , 10.1002/PSSA.2210710102
S. D. Hansen, C. R. Aita, Low temperature reactive sputter deposition of vanadium oxide Journal of Vacuum Science and Technology. ,vol. 3, pp. 660- 663 ,(1985) , 10.1116/1.572974
Takako Yoshino, Nobuyoshi Baba, Yasuo Kouda, Electrochromic Properties of V2O5 Thin Films Colloid-Chemically Deposited onto ITO Glasses Japanese Journal of Applied Physics. ,vol. 26, pp. 782- 783 ,(1987) , 10.1143/JJAP.26.782
I. Hamberg, C. G. Granqvist, Evaporated Sn‐doped In2O3films: Basic optical properties and applications to energy‐efficient windows Journal of Applied Physics. ,vol. 60, pp. R123- R160 ,(1986) , 10.1063/1.337534
K. West, B. Zachau-Christiansen, M.J.L. Østergård, T. Jacobsen, Vanadium oxides as electrode materials for rechargeable lithium cells Journal of Power Sources. ,vol. 20, pp. 165- 172 ,(1987) , 10.1016/0378-7753(87)80107-6
Stuart F. Cogan, Elizabeth J. Anderson, Timothy D. Plante, R. David Rauh, Electrochemical investigation of electrochromism in transparent conductive oxides. Applied Optics. ,vol. 24, pp. 2282- 2283 ,(1985) , 10.1364/AO.24.002282