Ionic conductivity of fluorite type crystals CaF2, SrF2, BaF2, and SrCl2 at high temperatures

作者: B.M Voronin , S.V Volkov

DOI: 10.1016/S0022-3697(01)00036-1

关键词: Melting pointCrystalliteConductivityIonArrhenius equationInorganic chemistryIonic conductivityMolar conductivityArrhenius plotThermodynamicsChemistry

摘要: … It was necessary, however, to overcome difficulties connected with the high melting temperatures of alkaline earth fluorides and corrosivity of their melts towards conventional materials …

参考文章(37)
M.A. Bredig, Order--disorder (lambda) transition in uranium dioxide and other solids of the fluorite type of structure Colloq. Int. Cent. Nat. Rech. Sci., no. 205, pp. 183-191. ,(1972)
Physics of superionic conductors Physics of Superionic Conductors. Series: Topics in Current Physics. ,vol. 15, ,(1979) , 10.1007/978-3-642-81328-3
M. T. Hutchings, Anion disorder in the fast‐ion phase of fluorites AIP Conf. Proc.; (United States). ,vol. 89, pp. 209- 220 ,(2008) , 10.1063/1.33672
V M Carr, A V Chadwick, R Saghafian, The electrical conductivity of PbF2 and SrCl2 crystals at high temperatures Journal of Physics C: Solid State Physics. ,vol. 11, ,(1978) , 10.1088/0022-3719/11/15/006
Herbert Schinke, Franz Sauerwald, Dichtemessungen. Über die Volumenänderung beim Schmelzen und den Schmelzprozeß bei anorganischen Salzen Zeitschrift für anorganische und allgemeine Chemie. ,vol. 304, pp. 25- 36 ,(1960) , 10.1002/ZAAC.19603040104
E. Barsis, A. Taylor, Interstitial Conduction in BaF2 Crystals Journal of Chemical Physics. ,vol. 48, pp. 4362- 4367 ,(1968) , 10.1063/1.1668000
A. S. Dworkin, M. A. Bredig, Heat Content and Entropy of Strontium Chloride from 298° to 1200° K. Journal of Chemical & Engineering Data. ,vol. 8, pp. 416- 417 ,(1963) , 10.1021/JE60018A038
A CHADWICK, High-temperature transport in fluorites Solid State Ionics. ,vol. 8, pp. 209- 220 ,(1983) , 10.1016/0167-2738(83)90018-8
A. Azimi, V.M. Carr, A.V. Chadwick, F.G. Kirkwood, R. Saghafian, Point defect parameters for β-PbF2 from a computer analysis of measurements of ionic conductivity Journal of Physics and Chemistry of Solids. ,vol. 45, pp. 23- 31 ,(1984) , 10.1016/0022-3697(84)90097-0